Aryl C-H activation by CuII to form an organometallic aryl-CuIII species: A novel twist on copper disproportionation

Xavi Ribas; Deanne A. Jackson; Bruno Donnadieu; José Mahía; Teodor Parella; Raül Xifra; Britt Hedman; Keith O. Hodgson; Antoni Llobet; T. Daniel P. Stack

doi:10.1002/1521-3773(20020816)41:16<2991::AID-ANIE2991>3.0.CO;2-6

Aryl C-H activation by Cu^II to form an organometallic aryl-Cu^III species: A novel twist on copper disproportionation

Xavi Ribas, Deanne A. Jackson, Bruno Donnadieu, José Mahía, Teodor Parella, Raül Xifra, Britt Hedman, Keith O. Hodgson, Antoni Llobet, T. Daniel P. Stack

Research output: Contribution to journal › Article › Research › peer-review

200 Citations (Scopus)

Abstract

Simple triazamacrocyclic ligands react with copper(II) salts under mild conditions to give the products of intramolecular aryl C-H activation and metal disproportionation [Eq. (1)]. The novel organometallic CuIII complexes thus formed are stable under protic conditions.

Original language	English
Pages (from-to)	2991-2994
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	16
DOIs	https://doi.org/10.1002/1521-3773(20020816)41:16<2991::AID-ANIE2991>3.0.CO;2-6
Publication status	Published - 16 Aug 2002

Keywords

C-H activation
Copper
Macrocyclic ligands
X-ray absorption

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10.1002/1521-3773(20020816)41:16<2991::AID-ANIE2991>3.0.CO;2-6

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Ribas, X., Jackson, D. A., Donnadieu, B., Mahía, J., Parella, T., Xifra, R., Hedman, B., Hodgson, K. O., Llobet, A., & Stack, T. D. P. (2002). Aryl C-H activation by Cu^II to form an organometallic aryl-Cu^III species: A novel twist on copper disproportionation. Angewandte Chemie - International Edition, 41(16), 2991-2994. https://doi.org/10.1002/1521-3773(20020816)41:16<2991::AID-ANIE2991>3.0.CO;2-6

Ribas, Xavi ; Jackson, Deanne A. ; Donnadieu, Bruno ; Mahía, José ; Parella, Teodor ; Xifra, Raül ; Hedman, Britt ; Hodgson, Keith O. ; Llobet, Antoni ; Stack, T. Daniel P. / Aryl C-H activation by Cu^II to form an organometallic aryl-Cu^III species: A novel twist on copper disproportionation. In: Angewandte Chemie - International Edition. 2002 ; Vol. 41, No. 16. pp. 2991-2994.

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abstract = "Simple triazamacrocyclic ligands react with copper(II) salts under mild conditions to give the products of intramolecular aryl C-H activation and metal disproportionation [Eq. (1)]. The novel organometallic CuIII complexes thus formed are stable under protic conditions.",

keywords = "C-H activation, Copper, Macrocyclic ligands, X-ray absorption",

author = "Xavi Ribas and Jackson, {Deanne A.} and Bruno Donnadieu and Jos{\'e} Mah{\'i}a and Teodor Parella and Ra{\"u}l Xifra and Britt Hedman and Hodgson, {Keith O.} and Antoni Llobet and Stack, {T. Daniel P.}",

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Ribas, X, Jackson, DA, Donnadieu, B, Mahía, J, Parella, T, Xifra, R, Hedman, B, Hodgson, KO, Llobet, A & Stack, TDP 2002, 'Aryl C-H activation by Cu^II to form an organometallic aryl-Cu^III species: A novel twist on copper disproportionation', Angewandte Chemie - International Edition, vol. 41, no. 16, pp. 2991-2994. https://doi.org/10.1002/1521-3773(20020816)41:16<2991::AID-ANIE2991>3.0.CO;2-6

Aryl C-H activation by Cu^II to form an organometallic aryl-Cu^III species: A novel twist on copper disproportionation. / Ribas, Xavi; Jackson, Deanne A.; Donnadieu, Bruno; Mahía, José; Parella, Teodor; Xifra, Raül; Hedman, Britt; Hodgson, Keith O.; Llobet, Antoni; Stack, T. Daniel P.

In: Angewandte Chemie - International Edition, Vol. 41, No. 16, 16.08.2002, p. 2991-2994.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - Aryl C-H activation by CuII to form an organometallic aryl-CuIII species: A novel twist on copper disproportionation

AU - Ribas, Xavi

AU - Jackson, Deanne A.

AU - Donnadieu, Bruno

AU - Mahía, José

AU - Parella, Teodor

AU - Xifra, Raül

AU - Hedman, Britt

AU - Hodgson, Keith O.

AU - Llobet, Antoni

AU - Stack, T. Daniel P.

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N2 - Simple triazamacrocyclic ligands react with copper(II) salts under mild conditions to give the products of intramolecular aryl C-H activation and metal disproportionation [Eq. (1)]. The novel organometallic CuIII complexes thus formed are stable under protic conditions.

AB - Simple triazamacrocyclic ligands react with copper(II) salts under mild conditions to give the products of intramolecular aryl C-H activation and metal disproportionation [Eq. (1)]. The novel organometallic CuIII complexes thus formed are stable under protic conditions.

KW - C-H activation

KW - Copper

KW - Macrocyclic ligands

KW - X-ray absorption

U2 - 10.1002/1521-3773(20020816)41:16<2991::AID-ANIE2991>3.0.CO;2-6

DO - 10.1002/1521-3773(20020816)41:16<2991::AID-ANIE2991>3.0.CO;2-6

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