Aqua(5,6-dimethyl-1,10-phenanthroline-N,N′)(malonato-O,O′) copper(II) hydrate

Laura Gasque, Rafael Moreno-Esparza, Elies Mollins, José Luis Briansó-Penalva, Lena Ruiz-Ramírez, Gerardo Medina-Dickinson

Research output: Contribution to journalArticleResearchpeer-review

13 Citations (Scopus)

Abstract

Each copper ion in the title complex, [Cu(C3H2O4)-(C14H12N 2)(H2O)]·H2O, displays a slightly distorted square-pyramidal coordination geometry, where the water molecule is in the apical position and two malonate O atoms and the phenanthroline N atoms define the base. The five-membered chelate ring defined by the phenanthroline molecule and the Cu atom is nearly planar with only slight distortion, while the ring defined by the malonate moiety and the Cu atom displays an envelope conformation. Hydrogen-bond and π-π* interactions define the crystal packing.
Original languageEnglish
Pages (from-to)158-160
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume55
Issue number2
DOIs
Publication statusPublished - 15 Feb 1999

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