Aqua(4,4′-dimethyl-2,2′-bipyridine-N,N′)-(malonato-O, O′)copper(II) dihydrate

Laura Gasque; Rafael Moreno-Esparza; Elies Mollins; José Luis Briansó-Penalva; Lena Ruiz-Ramírez; Gerardo Medina-Dickinson

doi:10.1107/S0108270198008178

Aqua(4,4′-dimethyl-2,2′-bipyridine-N,N′)-(malonato-O, O′)copper(II) dihydrate

Laura Gasque, Rafael Moreno-Esparza, Elies Mollins, José Luis Briansó-Penalva, Lena Ruiz-Ramírez, Gerardo Medina-Dickinson

Department of Geology

Research output: Contribution to journal › Article › Research › peer-review

17 Citations (Scopus)

Abstract

The title compound, [Cu(C3H2O4)(C12H12N 2)(H2O)].-2H2O, lies on a crystallographic mirror. The CuII ion in the complex has a slightly distorted square-pyramidal coordination environment, with one water molecule in the apical position, and two malonate O atoms and both N atoms of the bipyridine ligand defining the base. The five-membered chelate ring defined by atoms N1, C5, C5′, N1′ and Cu1 is almost planar, while the chelate ring defined by the malonate ligand (01, C7, C8, C7′ and O1′) and the Cu atom has an envelope conformation. Hydrogen bonding and π-π*-orbital interactions between the bipyridine rings seem to determine the crystal packing.

Original language	English
Pages (from-to)	1848-1850
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	12
DOIs	https://doi.org/10.1107/S0108270198008178
Publication status	Published - 15 Dec 1998

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10.1107/S0108270198008178

CCDC 130727: Experimental Crystal Structure Determination
Gasque, L. (Creator), Moreno-Esparza, R. (Creator), Mollins, E. (Creator), Briansó-Penalva, J. L. (Contributor), Ruiz-Ramírez, L. (Contributor) & Medina-Dickinson, G. (Creator), Cambridge Crystallographic Data Centre, 22 Jan 1999
DOI: 10.5517/cc4d10k, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4d10k&sid=DataCite
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title = "Aqua(4,4′-dimethyl-2,2′-bipyridine-N,N′)-(malonato-O, O′)copper(II) dihydrate",

abstract = "The title compound, [Cu(C3H2O4)(C12H12N 2)(H2O)].-2H2O, lies on a crystallographic mirror. The CuII ion in the complex has a slightly distorted square-pyramidal coordination environment, with one water molecule in the apical position, and two malonate O atoms and both N atoms of the bipyridine ligand defining the base. The five-membered chelate ring defined by atoms N1, C5, C5′, N1′ and Cu1 is almost planar, while the chelate ring defined by the malonate ligand (01, C7, C8, C7′ and O1′) and the Cu atom has an envelope conformation. Hydrogen bonding and π-π*-orbital interactions between the bipyridine rings seem to determine the crystal packing.",

author = "Laura Gasque and Rafael Moreno-Esparza and Elies Mollins and Brians{\'o}-Penalva, {Jos{\'e} Luis} and Lena Ruiz-Ram{\'i}rez and Gerardo Medina-Dickinson",

year = "1998",

month = dec,

day = "15",

doi = "10.1107/S0108270198008178",

language = "English",

volume = "54",

pages = "1848--1850",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "12",

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TY - JOUR

T1 - Aqua(4,4′-dimethyl-2,2′-bipyridine-N,N′)-(malonato-O, O′)copper(II) dihydrate

AU - Gasque, Laura

AU - Moreno-Esparza, Rafael

AU - Mollins, Elies

AU - Briansó-Penalva, José Luis

AU - Ruiz-Ramírez, Lena

AU - Medina-Dickinson, Gerardo

PY - 1998/12/15

Y1 - 1998/12/15

N2 - The title compound, [Cu(C3H2O4)(C12H12N 2)(H2O)].-2H2O, lies on a crystallographic mirror. The CuII ion in the complex has a slightly distorted square-pyramidal coordination environment, with one water molecule in the apical position, and two malonate O atoms and both N atoms of the bipyridine ligand defining the base. The five-membered chelate ring defined by atoms N1, C5, C5′, N1′ and Cu1 is almost planar, while the chelate ring defined by the malonate ligand (01, C7, C8, C7′ and O1′) and the Cu atom has an envelope conformation. Hydrogen bonding and π-π*-orbital interactions between the bipyridine rings seem to determine the crystal packing.

AB - The title compound, [Cu(C3H2O4)(C12H12N 2)(H2O)].-2H2O, lies on a crystallographic mirror. The CuII ion in the complex has a slightly distorted square-pyramidal coordination environment, with one water molecule in the apical position, and two malonate O atoms and both N atoms of the bipyridine ligand defining the base. The five-membered chelate ring defined by atoms N1, C5, C5′, N1′ and Cu1 is almost planar, while the chelate ring defined by the malonate ligand (01, C7, C8, C7′ and O1′) and the Cu atom has an envelope conformation. Hydrogen bonding and π-π*-orbital interactions between the bipyridine rings seem to determine the crystal packing.

U2 - 10.1107/S0108270198008178

DO - 10.1107/S0108270198008178

M3 - Article

SN - 0108-2701

VL - 54

SP - 1848

EP - 1850

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

Aqua(4,4′-dimethyl-2,2′-bipyridine-N,N′)-(malonato-O, O′)copper(II) dihydrate

Abstract

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Datasets

CCDC 130727: Experimental Crystal Structure Determination

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