Aqua(η4-1,5-cyclooctadiene)[1 -(2-methoxyethoxymethyl)-3,5- dimethylpyrazole]rhodium(I) tetrafluoroborate

Anna Boixassa; Rene Mathieu; Noël Lugan; Josefina Pons; Josep Ros

doi:10.1107/S1600536803016155

Aqua(η⁴-1,5-cyclooctadiene)[1 -(2-methoxyethoxymethyl)-3,5- dimethylpyrazole]rhodium(I) tetrafluoroborate

Anna Boixassa, Rene Mathieu, Noël Lugan, Josefina Pons, Josep Ros

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

4 Citations (Scopus)

Abstract

The title complex, [Rh(C8H12)(C9H 16N2O2)(H2O)](BF4) or [RhL(COD)(H2O)](BF4), is a monomer in the solid state. The RhI centre is in a square-planar arrangement. The four coordination sites are occupied by the N atom of the pyrazole ligand, the O atom from a water molecule and the centroids of the two cyclooctadiene olefin bonds. The structure is stabilized by hydrogen bonds between the coordinated water molecule and the two O atoms of the ether groups of the pyrazole ligand and one of the F atoms of the BF4 unit. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	8
DOIs	https://doi.org/10.1107/S1600536803016155
Publication status	Published - 1 Aug 2003

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Boixassa, A., Mathieu, R., Lugan, N., Pons, J., & Ros, J. (2003). Aqua(η⁴-1,5-cyclooctadiene)[1 -(2-methoxyethoxymethyl)-3,5- dimethylpyrazole]rhodium(I) tetrafluoroborate. Acta Crystallographica Section E: Structure Reports Online, 59(8). https://doi.org/10.1107/S1600536803016155

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title = "Aqua(η4-1,5-cyclooctadiene)[1 -(2-methoxyethoxymethyl)-3,5- dimethylpyrazole]rhodium(I) tetrafluoroborate",

abstract = "The title complex, [Rh(C8H12)(C9H 16N2O2)(H2O)](BF4) or [RhL(COD)(H2O)](BF4), is a monomer in the solid state. The RhI centre is in a square-planar arrangement. The four coordination sites are occupied by the N atom of the pyrazole ligand, the O atom from a water molecule and the centroids of the two cyclooctadiene olefin bonds. The structure is stabilized by hydrogen bonds between the coordinated water molecule and the two O atoms of the ether groups of the pyrazole ligand and one of the F atoms of the BF4 unit. {\textcopyright} 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.",

author = "Anna Boixassa and Rene Mathieu and No{\"e}l Lugan and Josefina Pons and Josep Ros",

year = "2003",

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T1 - Aqua(η4-1,5-cyclooctadiene)[1 -(2-methoxyethoxymethyl)-3,5- dimethylpyrazole]rhodium(I) tetrafluoroborate

AU - Boixassa, Anna

AU - Mathieu, Rene

AU - Lugan, Noël

AU - Pons, Josefina

AU - Ros, Josep

PY - 2003/8/1

Y1 - 2003/8/1

N2 - The title complex, [Rh(C8H12)(C9H 16N2O2)(H2O)](BF4) or [RhL(COD)(H2O)](BF4), is a monomer in the solid state. The RhI centre is in a square-planar arrangement. The four coordination sites are occupied by the N atom of the pyrazole ligand, the O atom from a water molecule and the centroids of the two cyclooctadiene olefin bonds. The structure is stabilized by hydrogen bonds between the coordinated water molecule and the two O atoms of the ether groups of the pyrazole ligand and one of the F atoms of the BF4 unit. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

AB - The title complex, [Rh(C8H12)(C9H 16N2O2)(H2O)](BF4) or [RhL(COD)(H2O)](BF4), is a monomer in the solid state. The RhI centre is in a square-planar arrangement. The four coordination sites are occupied by the N atom of the pyrazole ligand, the O atom from a water molecule and the centroids of the two cyclooctadiene olefin bonds. The structure is stabilized by hydrogen bonds between the coordinated water molecule and the two O atoms of the ether groups of the pyrazole ligand and one of the F atoms of the BF4 unit. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

U2 - 10.1107/S1600536803016155

DO - 10.1107/S1600536803016155

M3 - Article

VL - 59

IS - 8

ER -