An unprecedented α-C-C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex

Joelle Jaffart; Michel Etienne; Meike Reinhold; John E. McGrady; Feliu Maseras

doi:10.1039/b300324h

An unprecedented α-C-C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex

Joelle Jaffart, Michel Etienne, Meike Reinhold, John E. McGrady, Feliu Maseras

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

46 Citations (Scopus)

Abstract

Structural, spectroscopic and theoretical evidence indicate that an unusual α-C-C agostic interaction is preferred over both α- and β-C-H agostic alternatives in the title compound, TpMe2NbCl(c-C3H5)(MeCCMe). © 2003 Royal Society of Chemistry.

Original language	English
Pages (from-to)	876-877
Journal	Chemical Communications
Volume	3
Issue number	7
DOIs	https://doi.org/10.1039/b300324h
Publication status	Published - 1 Jan 2003

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title = "An unprecedented α-C-C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex",

abstract = "Structural, spectroscopic and theoretical evidence indicate that an unusual α-C-C agostic interaction is preferred over both α- and β-C-H agostic alternatives in the title compound, TpMe2NbCl(c-C3H5)(MeCCMe). {\textcopyright} 2003 Royal Society of Chemistry.",

author = "Joelle Jaffart and Michel Etienne and Meike Reinhold and McGrady, {John E.} and Feliu Maseras",

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T1 - An unprecedented α-C-C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex

AU - Jaffart, Joelle

AU - Etienne, Michel

AU - Reinhold, Meike

AU - McGrady, John E.

AU - Maseras, Feliu

PY - 2003/1/1

Y1 - 2003/1/1

N2 - Structural, spectroscopic and theoretical evidence indicate that an unusual α-C-C agostic interaction is preferred over both α- and β-C-H agostic alternatives in the title compound, TpMe2NbCl(c-C3H5)(MeCCMe). © 2003 Royal Society of Chemistry.

AB - Structural, spectroscopic and theoretical evidence indicate that an unusual α-C-C agostic interaction is preferred over both α- and β-C-H agostic alternatives in the title compound, TpMe2NbCl(c-C3H5)(MeCCMe). © 2003 Royal Society of Chemistry.

U2 - 10.1039/b300324h

DO - 10.1039/b300324h

M3 - Article

SN - 1359-7345

VL - 3

SP - 876

EP - 877

JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

An unprecedented α-C-C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex

Abstract

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