An improved route to the synthesis of μ-(alkane- or arene-thiolato)(μ-ethenyl)di-iron complexes. Crystal structure of μ-phenylmethanethiolato-μ-(1,2-diphenylethenyl)-hexacarbonyldi-iron(Fe-Fe)

Josep Ros; Josep M. Viñas; René Mathieu; Xavier Solans; Mercé Font-Bardía

doi:10.1039/DT9880000281

An improved route to the synthesis of μ-(alkane- or arene-thiolato)(μ-ethenyl)di-iron complexes. Crystal structure of μ-phenylmethanethiolato-μ-(1,2-diphenylethenyl)-hexacarbonyldi-iron(Fe-Fe)

Josep Ros, Josep M. Viñas, René Mathieu, Xavier Solans, Mercé Font-Bardía

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

21 Citations (Scopus)

Abstract

The reactions of [Fe<inf>2</inf>(CO)<inf>6</inf>(μ-Cl)(μ-CPh=CHPh)] with LiSR (R = Et, Pr<sup>i</sup>, cyclo-C<inf>6</inf>H<inf>11</inf>, Ph, or CH<inf>2</inf>Ph) lead to the complexes [Fe<inf>2</inf>(CO)<inf>6</inf>(μ-SR)(μ-CPh=CHPh)]. The structure of the benzyl derivative has been established by X-ray diffraction methods; crystals are monoclinic, space group P2<inf>1</inf>/n with a = 21.383(3), b = 7.098(2), c = 16.856(3), Å, β = 95.49(2)°, and Z = 4. The structure was solved and refined on the basis of 2 197 significant counter data, to a final R value of 0.056. The structure consists of Fe<inf>2</inf>(CO)<inf>6</inf> units with benzylthiolato and σ:η<sup>2</sup>-diphenylethenyl ligands bridging the two metal centres.

Original language	English
Pages (from-to)	281-284
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/DT9880000281
Publication status	Published - 1 Jan 1988

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Ros, J., Viñas, J. M., Mathieu, R., Solans, X., & Font-Bardía, M. (1988). An improved route to the synthesis of μ-(alkane- or arene-thiolato)(μ-ethenyl)di-iron complexes. Crystal structure of μ-phenylmethanethiolato-μ-(1,2-diphenylethenyl)-hexacarbonyldi-iron(Fe-Fe). Journal of the Chemical Society, Dalton Transactions, (2), 281-284. https://doi.org/10.1039/DT9880000281

@article{21f4efb965794ff7afbb9442efd7fc05,

title = "An improved route to the synthesis of μ-(alkane- or arene-thiolato)(μ-ethenyl)di-iron complexes. Crystal structure of μ-phenylmethanethiolato-μ-(1,2-diphenylethenyl)-hexacarbonyldi-iron(Fe-Fe)",

abstract = "The reactions of [Fe2(CO)6(μ-Cl)(μ-CPh=CHPh)] with LiSR (R = Et, Pri, cyclo-C6H11, Ph, or CH2Ph) lead to the complexes [Fe2(CO)6(μ-SR)(μ-CPh=CHPh)]. The structure of the benzyl derivative has been established by X-ray diffraction methods; crystals are monoclinic, space group P21/n with a = 21.383(3), b = 7.098(2), c = 16.856(3), {\AA}, β = 95.49(2)°, and Z = 4. The structure was solved and refined on the basis of 2 197 significant counter data, to a final R value of 0.056. The structure consists of Fe2(CO)6 units with benzylthiolato and σ:η2-diphenylethenyl ligands bridging the two metal centres.",

author = "Josep Ros and Vi{\~n}as, {Josep M.} and Ren{\'e} Mathieu and Xavier Solans and Merc{\'e} Font-Bard{\'i}a",

year = "1988",

month = jan,

day = "1",

doi = "10.1039/DT9880000281",

language = "English",

pages = "281--284",

number = "2",

}

Ros, J, Viñas, JM, Mathieu, R, Solans, X & Font-Bardía, M 1988, 'An improved route to the synthesis of μ-(alkane- or arene-thiolato)(μ-ethenyl)di-iron complexes. Crystal structure of μ-phenylmethanethiolato-μ-(1,2-diphenylethenyl)-hexacarbonyldi-iron(Fe-Fe)', Journal of the Chemical Society, Dalton Transactions, no. 2, pp. 281-284. https://doi.org/10.1039/DT9880000281

An improved route to the synthesis of μ-(alkane- or arene-thiolato)(μ-ethenyl)di-iron complexes. Crystal structure of μ-phenylmethanethiolato-μ-(1,2-diphenylethenyl)-hexacarbonyldi-iron(Fe-Fe). / Ros, Josep; Viñas, Josep M.; Mathieu, René et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 2, 01.01.1988, p. 281-284.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - An improved route to the synthesis of μ-(alkane- or arene-thiolato)(μ-ethenyl)di-iron complexes. Crystal structure of μ-phenylmethanethiolato-μ-(1,2-diphenylethenyl)-hexacarbonyldi-iron(Fe-Fe)

AU - Ros, Josep

AU - Viñas, Josep M.

AU - Mathieu, René

AU - Solans, Xavier

AU - Font-Bardía, Mercé

PY - 1988/1/1

Y1 - 1988/1/1

N2 - The reactions of [Fe2(CO)6(μ-Cl)(μ-CPh=CHPh)] with LiSR (R = Et, Pri, cyclo-C6H11, Ph, or CH2Ph) lead to the complexes [Fe2(CO)6(μ-SR)(μ-CPh=CHPh)]. The structure of the benzyl derivative has been established by X-ray diffraction methods; crystals are monoclinic, space group P21/n with a = 21.383(3), b = 7.098(2), c = 16.856(3), Å, β = 95.49(2)°, and Z = 4. The structure was solved and refined on the basis of 2 197 significant counter data, to a final R value of 0.056. The structure consists of Fe2(CO)6 units with benzylthiolato and σ:η2-diphenylethenyl ligands bridging the two metal centres.

AB - The reactions of [Fe2(CO)6(μ-Cl)(μ-CPh=CHPh)] with LiSR (R = Et, Pri, cyclo-C6H11, Ph, or CH2Ph) lead to the complexes [Fe2(CO)6(μ-SR)(μ-CPh=CHPh)]. The structure of the benzyl derivative has been established by X-ray diffraction methods; crystals are monoclinic, space group P21/n with a = 21.383(3), b = 7.098(2), c = 16.856(3), Å, β = 95.49(2)°, and Z = 4. The structure was solved and refined on the basis of 2 197 significant counter data, to a final R value of 0.056. The structure consists of Fe2(CO)6 units with benzylthiolato and σ:η2-diphenylethenyl ligands bridging the two metal centres.

U2 - 10.1039/DT9880000281

DO - 10.1039/DT9880000281

M3 - Article

SN - 1472-7773

SP - 281

EP - 284

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 2

ER -

An improved route to the synthesis of μ-(alkane- or arene-thiolato)(μ-ethenyl)di-iron complexes. Crystal structure of μ-phenylmethanethiolato-μ-(1,2-diphenylethenyl)-hexacarbonyldi-iron(Fe-Fe)

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