An Electrically Driven and Readable Molecular Monolayer Switch Based on a Solid Electrolyte

Elena Marchante, Núria Crivillers, Moritz Buhl, Jaume Veciana, Marta Mas-Torrent

    Research output: Contribution to journalArticleResearchpeer-review

    24 Citations (Scopus)


    © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. The potential application of molecular switches as active elements in information storage has been demonstrated through numerous works. Importantly, such switching capabilities have also been reported for self-assembled monolayers (SAMs). SAMs of electroactive molecules have recently been exploited as electrochemical switches. Typically, the state of these switches could be read out through their optical and/or magnetic response. These output reading processes are difficult to integrate into devices, and furthermore, there is a need to use liquid environments for switching the redox-active molecular systems. In this work, both of these challenges were overcome by using an ionic gel as the electrolyte medium, which led to an unprecedented solid-state device based on a single molecular layer. Moreover, electrochemical impedance has been successfully exploited as the output of the system.
    Original languageEnglish
    Pages (from-to)368-372
    JournalAngewandte Chemie - International Edition
    Issue number1
    Publication statusPublished - 4 Jan 2016


    • electrochemical impedance spectroscopy
    • ferrocene
    • molecular switches
    • self-assembled monolayers
    • solid electrolytes


    Dive into the research topics of 'An Electrically Driven and Readable Molecular Monolayer Switch Based on a Solid Electrolyte'. Together they form a unique fingerprint.

    Cite this