Aminopropylsilanes versus silatranes: An experimental and theoretical study

Ibon Alkorta, José Elguero, Alain Fruchier, Duncan J. Macquarrie, Albert Virgili

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30 Citations (Scopus)

Abstract

The 1H-, 13C-, 15N- and 29Si-NMR spectra of 3-aminopropyltrimethoxysilane and N,N-dimethylamino-propyltrimethoxysilane have been recorded. An analysis of the spectra together with GIAO calculations leads to the conclusion that these compounds exist as open-chain structures and not as ring-closed silatranes. The N→Si interaction is important only when there is at least one cycle in the structure, although two or three cycles (silatranes) are a more favorable disposition. © 2001 Elsevier Science B.V.
Original languageEnglish
Pages (from-to)148-153
JournalJournal of Organometallic Chemistry
Volume625
Issue number2
DOIs
Publication statusPublished - 22 Apr 2001

Keywords

  • 15 N-NMR
  • 29 Si-NMR
  • GIAO calculations
  • Silanes
  • Silatranes

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