Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones.

María E. Lloris; Jorge Marquet; Marcial Moreno-Mañas

doi:10.1016/S0040-4039(00)88524-X

Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones.

María E. Lloris, Jorge Marquet, Marcial Moreno-Mañas

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

13 Citations (Scopus)

Abstract

The copper(II) complexes of 3-methylpentane-2,4-dione and 2-methyl-1-phenylbutane-1,3-dione are good substrates for C-alkylation with several alkyl bromides including 1-bromoadamantane and 9-bromofluorene. Sterically congested β-diketones have been prepared. © 1990.

Original language	English
Pages (from-to)	7489-7492
Journal	Tetrahedron Letters
Volume	31
Issue number	51
DOIs	https://doi.org/10.1016/S0040-4039(00)88524-X
Publication status	Published - 1 Jan 1990

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title = "Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones.",

abstract = "The copper(II) complexes of 3-methylpentane-2,4-dione and 2-methyl-1-phenylbutane-1,3-dione are good substrates for C-alkylation with several alkyl bromides including 1-bromoadamantane and 9-bromofluorene. Sterically congested β-diketones have been prepared. {\textcopyright} 1990.",

author = "Lloris, {Mar{\'i}a E.} and Jorge Marquet and Marcial Moreno-Ma{\~n}as",

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T1 - Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones.

AU - Lloris, María E.

AU - Marquet, Jorge

AU - Moreno-Mañas, Marcial

PY - 1990/1/1

Y1 - 1990/1/1

N2 - The copper(II) complexes of 3-methylpentane-2,4-dione and 2-methyl-1-phenylbutane-1,3-dione are good substrates for C-alkylation with several alkyl bromides including 1-bromoadamantane and 9-bromofluorene. Sterically congested β-diketones have been prepared. © 1990.

AB - The copper(II) complexes of 3-methylpentane-2,4-dione and 2-methyl-1-phenylbutane-1,3-dione are good substrates for C-alkylation with several alkyl bromides including 1-bromoadamantane and 9-bromofluorene. Sterically congested β-diketones have been prepared. © 1990.

U2 - 10.1016/S0040-4039(00)88524-X

DO - 10.1016/S0040-4039(00)88524-X

M3 - Article

VL - 31

SP - 7489

EP - 7492

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 51

ER -

Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones.

Abstract

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