Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones.

María E. Lloris, Jorge Marquet, Marcial Moreno-Mañas

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13 Citations (Scopus)

Abstract

The copper(II) complexes of 3-methylpentane-2,4-dione and 2-methyl-1-phenylbutane-1,3-dione are good substrates for C-alkylation with several alkyl bromides including 1-bromoadamantane and 9-bromofluorene. Sterically congested β-diketones have been prepared. © 1990.
Original languageEnglish
Pages (from-to)7489-7492
JournalTetrahedron Letters
Volume31
Issue number51
DOIs
Publication statusPublished - 1 Jan 1990

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