TY - JOUR
T1 - Alkylation of β-diketones through their co(II), co(III) and zn(II) complexes. 1-Bromoadamantane as alkylating agent.
AU - González, A.
AU - Güell, F.
AU - Marquet, J.
AU - Moreno-Mañas, M.
PY - 1985/1/1
Y1 - 1985/1/1
N2 - α-(1-adamantyl)-β-diketones are now accessible by the alkylation of Co(II) complexes of β-diketones with 1-bromoadamantane. The intermediacy of adamantyl cation is proposed. Co(II), Co(III) and Zn(II) complexes of pentane-2,4-dione react with alkyl halides precursors of stabilized carbenium ions, to give 3-alkylpentane-2,4-diones. © 1985.
AB - α-(1-adamantyl)-β-diketones are now accessible by the alkylation of Co(II) complexes of β-diketones with 1-bromoadamantane. The intermediacy of adamantyl cation is proposed. Co(II), Co(III) and Zn(II) complexes of pentane-2,4-dione react with alkyl halides precursors of stabilized carbenium ions, to give 3-alkylpentane-2,4-diones. © 1985.
U2 - 10.1016/S0040-4039(00)89236-9
DO - 10.1016/S0040-4039(00)89236-9
M3 - Article
VL - 26
SP - 3735
EP - 3738
IS - 31
ER -