Alkylation of β-diketones through their co(II), co(III) and zn(II) complexes. 1-Bromoadamantane as alkylating agent.

A. González; F. Güell; J. Marquet; M. Moreno-Mañas

doi:10.1016/S0040-4039(00)89236-9

Alkylation of β-diketones through their co(II), co(III) and zn(II) complexes. 1-Bromoadamantane as alkylating agent.

A. González, F. Güell, J. Marquet, M. Moreno-Mañas

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

25 Citations (Scopus)

Abstract

α-(1-adamantyl)-β-diketones are now accessible by the alkylation of Co(II) complexes of β-diketones with 1-bromoadamantane. The intermediacy of adamantyl cation is proposed. Co(II), Co(III) and Zn(II) complexes of pentane-2,4-dione react with alkyl halides precursors of stabilized carbenium ions, to give 3-alkylpentane-2,4-diones. © 1985.

Original language	English
Pages (from-to)	3735-3738
Journal	Tetrahedron Letters
Volume	26
Issue number	31
DOIs	https://doi.org/10.1016/S0040-4039(00)89236-9
Publication status	Published - 1 Jan 1985

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title = "Alkylation of β-diketones through their co(II), co(III) and zn(II) complexes. 1-Bromoadamantane as alkylating agent.",

abstract = "α-(1-adamantyl)-β-diketones are now accessible by the alkylation of Co(II) complexes of β-diketones with 1-bromoadamantane. The intermediacy of adamantyl cation is proposed. Co(II), Co(III) and Zn(II) complexes of pentane-2,4-dione react with alkyl halides precursors of stabilized carbenium ions, to give 3-alkylpentane-2,4-diones. {\textcopyright} 1985.",

author = "A. Gonz{\'a}lez and F. G{\"u}ell and J. Marquet and M. Moreno-Ma{\~n}as",

year = "1985",

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doi = "10.1016/S0040-4039(00)89236-9",

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T1 - Alkylation of β-diketones through their co(II), co(III) and zn(II) complexes. 1-Bromoadamantane as alkylating agent.

AU - González, A.

AU - Güell, F.

AU - Marquet, J.

AU - Moreno-Mañas, M.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - α-(1-adamantyl)-β-diketones are now accessible by the alkylation of Co(II) complexes of β-diketones with 1-bromoadamantane. The intermediacy of adamantyl cation is proposed. Co(II), Co(III) and Zn(II) complexes of pentane-2,4-dione react with alkyl halides precursors of stabilized carbenium ions, to give 3-alkylpentane-2,4-diones. © 1985.

AB - α-(1-adamantyl)-β-diketones are now accessible by the alkylation of Co(II) complexes of β-diketones with 1-bromoadamantane. The intermediacy of adamantyl cation is proposed. Co(II), Co(III) and Zn(II) complexes of pentane-2,4-dione react with alkyl halides precursors of stabilized carbenium ions, to give 3-alkylpentane-2,4-diones. © 1985.

U2 - 10.1016/S0040-4039(00)89236-9

DO - 10.1016/S0040-4039(00)89236-9

M3 - Article

VL - 26

SP - 3735

EP - 3738

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 31

ER -

Alkylation of β-diketones through their co(II), co(III) and zn(II) complexes. 1-Bromoadamantane as alkylating agent.

Abstract

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