{Ag<inf>5</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>)<inf>3</inf>-NHMe <inf>2</inf>]<inf>3</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>) <inf>3</inf>-NMe<inf>2</inf>]<inf>3</inf>}2+, the first thiolate complex of a metal with trigonal bipyramido-M<inf>5</inf>-trigonal prismo-S <inf>6</inf> polyhedral stereochemistry

Pilar González-Duarte; Joan Sola; Josep Vives; Xavier Solans

doi:10.1039/C39870001641

{Ag<inf>5</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>)<inf>3</inf>-NHMe <inf>2</inf>]<inf>3</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>) <inf>3</inf>-NMe<inf>2</inf>]<inf>3</inf>}2+, the first thiolate complex of a metal with trigonal bipyramido-M<inf>5</inf>-trigonal prismo-S <inf>6</inf> polyhedral stereochemistry

Pilar González-Duarte, Joan Sola, Josep Vives, Xavier Solans

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

22 Citations (Scopus)

Abstract

The synthesis and structure of {Ag5[μ2-S-(CH 2)3-NHMe2]3[μ2-S- (CH2)3-NMe2]3}(ClO4) 2; the Ag5S6 core of the cage cation provides the only known case of an [Mx(SR)y] aggregate that can be described as a trigonal bipyramid of metal atoms enclosed within a regular trigonal prism of doubly bridging thiolate ligands.

Original language	English
Pages (from-to)	1641-1642
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39870001641
Publication status	Published - 1 Dec 1987

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González-Duarte, P., Sola, J., Vives, J., & Solans, X. (1987). {Ag<inf>5</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>)<inf>3</inf>-NHMe <inf>2</inf>]<inf>3</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>) <inf>3</inf>-NMe<inf>2</inf>]<inf>3</inf>}2+, the first thiolate complex of a metal with trigonal bipyramido-M<inf>5</inf>-trigonal prismo-S <inf>6</inf> polyhedral stereochemistry. Journal of the Chemical Society D: Chemical Communications, (21), 1641-1642. https://doi.org/10.1039/C39870001641

González-Duarte, Pilar ; Sola, Joan ; Vives, Josep ; Solans, Xavier. / {Ag<inf>5</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>)<inf>3</inf>-NHMe <inf>2</inf>]<inf>3</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>) <inf>3</inf>-NMe<inf>2</inf>]<inf>3</inf>}2+, the first thiolate complex of a metal with trigonal bipyramido-M<inf>5</inf>-trigonal prismo-S <inf>6</inf> polyhedral stereochemistry. In: Journal of the Chemical Society D: Chemical Communications. 1987 ; No. 21. pp. 1641-1642.

@article{59912a471487410da1abfd228775af08,

title = "{Ag5[μ2-S-(CH2)3-NHMe 2]3[μ2-S-(CH2) 3-NMe2]3}2+, the first thiolate complex of a metal with trigonal bipyramido-M5-trigonal prismo-S 6 polyhedral stereochemistry",

abstract = "The synthesis and structure of {Ag5[μ2-S-(CH 2)3-NHMe2]3[μ2-S- (CH2)3-NMe2]3}(ClO4) 2; the Ag5S6 core of the cage cation provides the only known case of an [Mx(SR)y] aggregate that can be described as a trigonal bipyramid of metal atoms enclosed within a regular trigonal prism of doubly bridging thiolate ligands.",

author = "Pilar Gonz{\'a}lez-Duarte and Joan Sola and Josep Vives and Xavier Solans",

year = "1987",

month = dec,

day = "1",

doi = "10.1039/C39870001641",

language = "English",

pages = "1641--1642",

number = "21",

}

González-Duarte, P, Sola, J, Vives, J & Solans, X 1987, '{Ag<inf>5</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>)<inf>3</inf>-NHMe <inf>2</inf>]<inf>3</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>) <inf>3</inf>-NMe<inf>2</inf>]<inf>3</inf>}2+, the first thiolate complex of a metal with trigonal bipyramido-M<inf>5</inf>-trigonal prismo-S <inf>6</inf> polyhedral stereochemistry', Journal of the Chemical Society D: Chemical Communications, no. 21, pp. 1641-1642. https://doi.org/10.1039/C39870001641

{Ag<inf>5</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>)<inf>3</inf>-NHMe <inf>2</inf>]<inf>3</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>) <inf>3</inf>-NMe<inf>2</inf>]<inf>3</inf>}2+, the first thiolate complex of a metal with trigonal bipyramido-M<inf>5</inf>-trigonal prismo-S <inf>6</inf> polyhedral stereochemistry. / González-Duarte, Pilar; Sola, Joan; Vives, Josep; Solans, Xavier.

In: Journal of the Chemical Society D: Chemical Communications, No. 21, 01.12.1987, p. 1641-1642.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - {Ag5[μ2-S-(CH2)3-NHMe 2]3[μ2-S-(CH2) 3-NMe2]3}2+, the first thiolate complex of a metal with trigonal bipyramido-M5-trigonal prismo-S 6 polyhedral stereochemistry

AU - González-Duarte, Pilar

AU - Sola, Joan

AU - Vives, Josep

AU - Solans, Xavier

PY - 1987/12/1

Y1 - 1987/12/1

N2 - The synthesis and structure of {Ag5[μ2-S-(CH 2)3-NHMe2]3[μ2-S- (CH2)3-NMe2]3}(ClO4) 2; the Ag5S6 core of the cage cation provides the only known case of an [Mx(SR)y] aggregate that can be described as a trigonal bipyramid of metal atoms enclosed within a regular trigonal prism of doubly bridging thiolate ligands.

AB - The synthesis and structure of {Ag5[μ2-S-(CH 2)3-NHMe2]3[μ2-S- (CH2)3-NMe2]3}(ClO4) 2; the Ag5S6 core of the cage cation provides the only known case of an [Mx(SR)y] aggregate that can be described as a trigonal bipyramid of metal atoms enclosed within a regular trigonal prism of doubly bridging thiolate ligands.

U2 - 10.1039/C39870001641

DO - 10.1039/C39870001641

M3 - Article

SP - 1641

EP - 1642

IS - 21

ER -

González-Duarte P, Sola J, Vives J, Solans X. {Ag<inf>5</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>)<inf>3</inf>-NHMe <inf>2</inf>]<inf>3</inf>[μ<inf>2</inf>-S-(CH<inf>2</inf>) <inf>3</inf>-NMe<inf>2</inf>]<inf>3</inf>}2+, the first thiolate complex of a metal with trigonal bipyramido-M<inf>5</inf>-trigonal prismo-S <inf>6</inf> polyhedral stereochemistry. Journal of the Chemical Society D: Chemical Communications. 1987 Dec 1;(21):1641-1642. https://doi.org/10.1039/C39870001641