Acid catalysis in cycloaddition reactions

J. Bertran; V. Branchadell; M. Duran; A. Oliva

doi:10.1016/0166-1280(84)80054-8

Acid catalysis in cycloaddition reactions

J. Bertran, V. Branchadell, M. Duran, A. Oliva

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

2 Citations (Scopus)

Abstract

By means of the MINDO/3 method, the effect of acid catalysis on a Diels-Alder and a polar 2+2 cycloaddition reactions has been studied. A proton and a NH3-solvated proton have been used as catalysts. The main effect of the catalyst is to change the mechanism of the studied reactions by increasing the two-step character of the processes. Charge transfer plays a decisive role in the change of the mechanism. The intervention of the geometrical parameters of the catalyst on the reaction coordinate is analysed. © 1984.

Original language	English
Pages (from-to)	191-196
Journal	Journal of Molecular Structure: THEOCHEM
Volume	107
Issue number	C
DOIs	https://doi.org/10.1016/0166-1280(84)80054-8
Publication status	Published - 1 Jan 1984

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title = "Acid catalysis in cycloaddition reactions",

abstract = "By means of the MINDO/3 method, the effect of acid catalysis on a Diels-Alder and a polar 2+2 cycloaddition reactions has been studied. A proton and a NH3-solvated proton have been used as catalysts. The main effect of the catalyst is to change the mechanism of the studied reactions by increasing the two-step character of the processes. Charge transfer plays a decisive role in the change of the mechanism. The intervention of the geometrical parameters of the catalyst on the reaction coordinate is analysed. {\textcopyright} 1984.",

author = "J. Bertran and V. Branchadell and M. Duran and A. Oliva",

year = "1984",

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doi = "10.1016/0166-1280(84)80054-8",

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TY - JOUR

T1 - Acid catalysis in cycloaddition reactions

AU - Bertran, J.

AU - Branchadell, V.

AU - Duran, M.

AU - Oliva, A.

PY - 1984/1/1

Y1 - 1984/1/1

N2 - By means of the MINDO/3 method, the effect of acid catalysis on a Diels-Alder and a polar 2+2 cycloaddition reactions has been studied. A proton and a NH3-solvated proton have been used as catalysts. The main effect of the catalyst is to change the mechanism of the studied reactions by increasing the two-step character of the processes. Charge transfer plays a decisive role in the change of the mechanism. The intervention of the geometrical parameters of the catalyst on the reaction coordinate is analysed. © 1984.

AB - By means of the MINDO/3 method, the effect of acid catalysis on a Diels-Alder and a polar 2+2 cycloaddition reactions has been studied. A proton and a NH3-solvated proton have been used as catalysts. The main effect of the catalyst is to change the mechanism of the studied reactions by increasing the two-step character of the processes. Charge transfer plays a decisive role in the change of the mechanism. The intervention of the geometrical parameters of the catalyst on the reaction coordinate is analysed. © 1984.

U2 - 10.1016/0166-1280(84)80054-8

DO - 10.1016/0166-1280(84)80054-8

M3 - Article

SN - 0166-1280

VL - 107

SP - 191

EP - 196

JO - Journal of Molecular Structure: THEOCHEM

JF - Journal of Molecular Structure: THEOCHEM

IS - C

ER -

Acid catalysis in cycloaddition reactions

Abstract

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