A versatile and highly stereocontrolled synthetic approach to homochiral polyfunctional norbornene and norbornane derivatives

Ramon Casas; Javier Ibarzo; José M. Jiménez; Rosa M. Ortuño

doi:10.1016/S0957-4166(00)80174-3

A versatile and highly stereocontrolled synthetic approach to homochiral polyfunctional norbornene and norbornane derivatives

Ramon Casas, Javier Ibarzo, José M. Jiménez, Rosa M. Ortuño

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

9 Citations (Scopus)

Abstract

Several title compounds have been synthesized from D-mannitol as the unique chiral precursor. The target molecules include pairs of enantiomers and their configuration has mainly been assured by controlling the facial and the endo/exo diastereoselectivity in the Diels-Alder reactions of chiral cyclic or acyclic dienophiles. Some of the products obtained are key intermediates in the synthesis of biologically active compounds. © 1993.

Original language	English
Pages (from-to)	669-680
Journal	Tetrahedron: asymmetry
Volume	4
Issue number	4
DOIs	https://doi.org/10.1016/S0957-4166(00)80174-3
Publication status	Published - 1 Jan 1993

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title = "A versatile and highly stereocontrolled synthetic approach to homochiral polyfunctional norbornene and norbornane derivatives",

abstract = "Several title compounds have been synthesized from D-mannitol as the unique chiral precursor. The target molecules include pairs of enantiomers and their configuration has mainly been assured by controlling the facial and the endo/exo diastereoselectivity in the Diels-Alder reactions of chiral cyclic or acyclic dienophiles. Some of the products obtained are key intermediates in the synthesis of biologically active compounds. {\textcopyright} 1993.",

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T1 - A versatile and highly stereocontrolled synthetic approach to homochiral polyfunctional norbornene and norbornane derivatives

AU - Casas, Ramon

AU - Ibarzo, Javier

AU - Jiménez, José M.

AU - Ortuño, Rosa M.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - Several title compounds have been synthesized from D-mannitol as the unique chiral precursor. The target molecules include pairs of enantiomers and their configuration has mainly been assured by controlling the facial and the endo/exo diastereoselectivity in the Diels-Alder reactions of chiral cyclic or acyclic dienophiles. Some of the products obtained are key intermediates in the synthesis of biologically active compounds. © 1993.

AB - Several title compounds have been synthesized from D-mannitol as the unique chiral precursor. The target molecules include pairs of enantiomers and their configuration has mainly been assured by controlling the facial and the endo/exo diastereoselectivity in the Diels-Alder reactions of chiral cyclic or acyclic dienophiles. Some of the products obtained are key intermediates in the synthesis of biologically active compounds. © 1993.

U2 - 10.1016/S0957-4166(00)80174-3

DO - 10.1016/S0957-4166(00)80174-3

M3 - Article

VL - 4

SP - 669

EP - 680

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ER -

A versatile and highly stereocontrolled synthetic approach to homochiral polyfunctional norbornene and norbornane derivatives

Abstract

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