A stable, mononuclear, cationic Pt(III) complex stabilised by bulky N-heterocyclic carbenes

Orestes Rivada-Wheelaghan; Manuel A. Ortuño; Sergio E. García-Garrido; Josefina Díez; Pablo J. Alonso; Agustí Lledós; Salvador Conejero

doi:10.1039/c3cc48553f

A stable, mononuclear, cationic Pt(III) complex stabilised by bulky N-heterocyclic carbenes

Orestes Rivada-Wheelaghan, Manuel A. Ortuño, Sergio E. García-Garrido, Josefina Díez, Pablo J. Alonso, Agustí Lledós, Salvador Conejero

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

The thermally stable, paramagnetic Pt(III) complex [PtI2(IPr) 2][BArF] has been prepared by oxidation of the Pt(ii) complex [PtI2(IPr)2] with iodine in the presence of NaBArF. X-ray crystallographic studies revealed the mononuclear nature of this species with a square-planar geometry. EPR and DFT studies pointed out to a metal-centred radical. © The Royal Society of Chemistry.

Original language	English
Pages (from-to)	1299-1301
Journal	Chemical Communications
Volume	50
Issue number	11
DOIs	https://doi.org/10.1039/c3cc48553f
Publication status	Published - 9 Feb 2014

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title = "A stable, mononuclear, cationic Pt(III) complex stabilised by bulky N-heterocyclic carbenes",

abstract = "The thermally stable, paramagnetic Pt(III) complex [PtI2(IPr) 2][BArF] has been prepared by oxidation of the Pt(ii) complex [PtI2(IPr)2] with iodine in the presence of NaBArF. X-ray crystallographic studies revealed the mononuclear nature of this species with a square-planar geometry. EPR and DFT studies pointed out to a metal-centred radical. {\textcopyright} The Royal Society of Chemistry.",

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year = "2014",

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A stable, mononuclear, cationic Pt(III) complex stabilised by bulky N-heterocyclic carbenes. / Rivada-Wheelaghan, Orestes; Ortuño, Manuel A.; García-Garrido, Sergio E.; Díez, Josefina; Alonso, Pablo J.; Lledós, Agustí; Conejero, Salvador.

In: Chemical Communications, Vol. 50, No. 11, 09.02.2014, p. 1299-1301.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - A stable, mononuclear, cationic Pt(III) complex stabilised by bulky N-heterocyclic carbenes

AU - Rivada-Wheelaghan, Orestes

AU - Ortuño, Manuel A.

AU - García-Garrido, Sergio E.

AU - Díez, Josefina

AU - Alonso, Pablo J.

AU - Lledós, Agustí

AU - Conejero, Salvador

PY - 2014/2/9

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AB - The thermally stable, paramagnetic Pt(III) complex [PtI2(IPr) 2][BArF] has been prepared by oxidation of the Pt(ii) complex [PtI2(IPr)2] with iodine in the presence of NaBArF. X-ray crystallographic studies revealed the mononuclear nature of this species with a square-planar geometry. EPR and DFT studies pointed out to a metal-centred radical. © The Royal Society of Chemistry.

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DO - 10.1039/c3cc48553f

M3 - Article

VL - 50

SP - 1299

EP - 1301

IS - 11

ER -

A stable, mononuclear, cationic Pt(III) complex stabilised by bulky N-heterocyclic carbenes

Abstract

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