A Stable Monomeric SiO<inf>2</inf> Complex with Donor–Acceptor Ligands

Ricardo Rodriguez, David Gau, Jérémy Saouli, Antoine Baceiredo, Nathalie Saffon-Merceron, Vicenç Branchadell, Tsuyoshi Kato

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20 Citations (Scopus)

Abstract

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Isolation of a monomeric SiO2 compound 3 as a stable donor–acceptor complex with two different ligands —a σ-donating ligand (pyridine, dimethylaminopyridine, N-heterocyclic carbene) and a donor–acceptor ligand (iminophosphorane)—is presented. The SiO2 complex 3 is soluble in ordinary organic solvents and is stable at room temperature in solution and in the solid state. Of particular interest, 3 remains reactive and can be used as a stable and soluble unimolecular SiO2 reagent.
Original languageEnglish
Pages (from-to)3935-3939
JournalAngewandte Chemie - International Edition
Volume56
Issue number14
DOIs
Publication statusPublished - 1 Jan 2017

Keywords

  • silanone
  • silicon
  • silicon dioxide
  • SiO complexes 2

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