A Stable Monomeric SiO<inf>2</inf> Complex with Donor–Acceptor Ligands

Ricardo Rodriguez; David Gau; Jérémy Saouli; Antoine Baceiredo; Nathalie Saffon-Merceron; Vicenç Branchadell; Tsuyoshi Kato

doi:10.1002/anie.201611851

A Stable Monomeric SiO<inf>2</inf> Complex with Donor–Acceptor Ligands

Ricardo Rodriguez, David Gau, Jérémy Saouli, Antoine Baceiredo, Nathalie Saffon-Merceron, Vicenç Branchadell, Tsuyoshi Kato

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Isolation of a monomeric SiO2 compound 3 as a stable donor–acceptor complex with two different ligands —a σ-donating ligand (pyridine, dimethylaminopyridine, N-heterocyclic carbene) and a donor–acceptor ligand (iminophosphorane)—is presented. The SiO2 complex 3 is soluble in ordinary organic solvents and is stable at room temperature in solution and in the solid state. Of particular interest, 3 remains reactive and can be used as a stable and soluble unimolecular SiO2 reagent.

Original language	English
Pages (from-to)	3935-3939
Journal	Angewandte Chemie - International Edition
Volume	56
Issue number	14
DOIs	https://doi.org/10.1002/anie.201611851
Publication status	Published - 1 Jan 2017

Keywords

silanone
silicon
silicon dioxide
SiO complexes 2

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10.1002/anie.201611851

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title = "A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands",

abstract = "{\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Isolation of a monomeric SiO2 compound 3 as a stable donor–acceptor complex with two different ligands —a σ-donating ligand (pyridine, dimethylaminopyridine, N-heterocyclic carbene) and a donor–acceptor ligand (iminophosphorane)—is presented. The SiO2 complex 3 is soluble in ordinary organic solvents and is stable at room temperature in solution and in the solid state. Of particular interest, 3 remains reactive and can be used as a stable and soluble unimolecular SiO2 reagent.",

keywords = "silanone, silicon, silicon dioxide, SiO complexes 2",

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year = "2017",

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A Stable Monomeric SiO<inf>2</inf> Complex with Donor–Acceptor Ligands. / Rodriguez, Ricardo; Gau, David; Saouli, Jérémy; Baceiredo, Antoine; Saffon-Merceron, Nathalie; Branchadell, Vicenç; Kato, Tsuyoshi.

In: Angewandte Chemie - International Edition, Vol. 56, No. 14, 01.01.2017, p. 3935-3939.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands

AU - Rodriguez, Ricardo

AU - Gau, David

AU - Saouli, Jérémy

AU - Baceiredo, Antoine

AU - Saffon-Merceron, Nathalie

AU - Branchadell, Vicenç

AU - Kato, Tsuyoshi

PY - 2017/1/1

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AB - © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Isolation of a monomeric SiO2 compound 3 as a stable donor–acceptor complex with two different ligands —a σ-donating ligand (pyridine, dimethylaminopyridine, N-heterocyclic carbene) and a donor–acceptor ligand (iminophosphorane)—is presented. The SiO2 complex 3 is soluble in ordinary organic solvents and is stable at room temperature in solution and in the solid state. Of particular interest, 3 remains reactive and can be used as a stable and soluble unimolecular SiO2 reagent.

KW - silanone

KW - silicon

KW - silicon dioxide

KW - SiO complexes 2

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DO - 10.1002/anie.201611851

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JO - Angewandte Chemie - International Edition

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