A novel Rh-B σ bond. Crystal structure of [N(CH<inf>3</inf>) <inf>4</inf>][RhCl{7,8-μ-S(CH<inf>2</inf>CH<inf>2</inf>)S-C<inf>2</inf>B <inf>9</inf>H<inf>10</inf>}{σ-7,8-μ-S(CH<inf>2</inf>CH <inf>2</inf>)S-C<inf>2</inf>B<inf>9</inf>H<inf>9</inf>}]

Francesc Teixidor, Antonio Romerosa, Clara Viñas, Jordi Rius, Carles Miravittles, Jaume Casabó

Research output: Contribution to journalArticleResearchpeer-review

30 Citations (Scopus)

Abstract

The complex [N(CH3)4][RhCl{7,8-μ-S(CH 2CH2)S-C2B9H10} {σ-7,8-μ-S(CH2CH2)S-C2B 9H9}] is an octahedral Rh(III) complex; the sixth coordination site is occupied by a σ-bond B-Rh in this first example of B(3)-Rh coordination.
Original languageEnglish
Pages (from-to)192-193
JournalJournal of the Chemical Society, Chemical Communications
Issue number3
DOIs
Publication statusPublished - 1 Dec 1991

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