A new hexaferrocene complex with a [M<inf>3</inf>(μ<inf>3</inf>-O)] <sup>7+</sup> core

Valeriu Mereacre, Motohiro Nakano, Jordi Gómez-Segura, Inhar Imaz, Christian Sporer, Klaus Wurst, Jaume Veciana, Constantin Turta, Daniel Ruiz-Molina, Peter Jaitner

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    20 Citations (Scopus)


    The new hexaferrocene complex 1 has been synthesized and characterized by X-ray diffraction. Its magnetization data were fitted to a detailed theoretical model that considers nonequivalent exchange parameters between Fe ions to yield the magnetic exchange coupling values of J1/kB = -31.5 K and J2/kB = -25.8 K. Moreover, the cyclic voltammogram of complex 1 confirmed its redox activity associated with the presence of ferrocene units, with very small or negligible electronic interactions between them. © 2006 American Chemical Society.
    Original languageEnglish
    Pages (from-to)10443-10445
    JournalInorganic Chemistry
    Issue number26
    Publication statusPublished - 25 Dec 2006


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