A new hexaferrocene complex with a [M<inf>3</inf>(μ<inf>3</inf>-O)] 7+ core

Valeriu Mereacre; Motohiro Nakano; Jordi Gómez-Segura; Inhar Imaz; Christian Sporer; Klaus Wurst; Jaume Veciana; Constantin Turta; Daniel Ruiz-Molina; Peter Jaitner

doi:10.1021/ic061322s

A new hexaferrocene complex with a [M<inf>3</inf>(μ<inf>3</inf>-O)] 7+ core

Valeriu Mereacre, Motohiro Nakano, Jordi Gómez-Segura, Inhar Imaz, Christian Sporer, Klaus Wurst, Jaume Veciana, Constantin Turta, Daniel Ruiz-Molina, Peter Jaitner

Research output: Contribution to journal › Article › Research › peer-review

18 Citations (Scopus)

Abstract

The new hexaferrocene complex 1 has been synthesized and characterized by X-ray diffraction. Its magnetization data were fitted to a detailed theoretical model that considers nonequivalent exchange parameters between Fe ions to yield the magnetic exchange coupling values of J1/kB = -31.5 K and J2/kB = -25.8 K. Moreover, the cyclic voltammogram of complex 1 confirmed its redox activity associated with the presence of ferrocene units, with very small or negligible electronic interactions between them. © 2006 American Chemical Society.

Original language	English
Pages (from-to)	10443-10445
Journal	Inorganic Chemistry
Volume	45
Issue number	26
DOIs	https://doi.org/10.1021/ic061322s
Publication status	Published - 25 Dec 2006

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10.1021/ic061322s

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A new hexaferrocene complex with a [M<inf>3</inf>(μ<inf>3</inf>-O)] 7+ core. / Mereacre, Valeriu; Nakano, Motohiro; Gómez-Segura, Jordi; Imaz, Inhar; Sporer, Christian; Wurst, Klaus; Veciana, Jaume; Turta, Constantin; Ruiz-Molina, Daniel; Jaitner, Peter.

In: Inorganic Chemistry, Vol. 45, No. 26, 25.12.2006, p. 10443-10445.

Research output: Contribution to journal › Article › Research › peer-review

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AU - Mereacre, Valeriu

AU - Nakano, Motohiro

AU - Gómez-Segura, Jordi

AU - Imaz, Inhar

AU - Sporer, Christian

AU - Wurst, Klaus

AU - Veciana, Jaume

AU - Turta, Constantin

AU - Ruiz-Molina, Daniel

AU - Jaitner, Peter

PY - 2006/12/25

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AB - The new hexaferrocene complex 1 has been synthesized and characterized by X-ray diffraction. Its magnetization data were fitted to a detailed theoretical model that considers nonequivalent exchange parameters between Fe ions to yield the magnetic exchange coupling values of J1/kB = -31.5 K and J2/kB = -25.8 K. Moreover, the cyclic voltammogram of complex 1 confirmed its redox activity associated with the presence of ferrocene units, with very small or negligible electronic interactions between them. © 2006 American Chemical Society.

U2 - 10.1021/ic061322s

DO - 10.1021/ic061322s

M3 - Article

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EP - 10445

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A new hexaferrocene complex with a [M<inf>3</inf>(μ<inf>3</inf>-O)] <sup>7+</sup> core

Abstract

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