Abstract
The new hexaferrocene complex 1 has been synthesized and characterized by X-ray diffraction. Its magnetization data were fitted to a detailed theoretical model that considers nonequivalent exchange parameters between Fe ions to yield the magnetic exchange coupling values of J1/kB = -31.5 K and J2/kB = -25.8 K. Moreover, the cyclic voltammogram of complex 1 confirmed its redox activity associated with the presence of ferrocene units, with very small or negligible electronic interactions between them. © 2006 American Chemical Society.
Original language | English |
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Pages (from-to) | 10443-10445 |
Journal | Inorganic Chemistry |
Volume | 45 |
Issue number | 26 |
DOIs | |
Publication status | Published - 25 Dec 2006 |