A measureable equilibrium between iridium hydride alkylidene and iridium hydride alkene isomeres

Margarita Paneque, Manuel L. Poveda, Laura L. Santos, Ernesto Carmona, Agustí Lledós, Gregori Ujaque, Kurt Mereiter

Research output: Contribution to journalArticleResearchpeer-review

42 Citations (Scopus)

Abstract

An almost thermoneutral equilibrium mixture of hydride alkylidene 1 and hydride alkene 2 (see scheme) is feasible with a TpMe2Ir III system (Tp is tris(pyrazolyl)borate) through its reaction with o-C6H4(OH)CH2CH3 under activation of sp3 C-H bonds.
Original languageEnglish
Pages (from-to)3708-3711
JournalAngewandte Chemie - International Edition
Volume43
Issue number28
DOIs
Publication statusPublished - 12 Jul 2004

Keywords

  • Alkene ligands
  • C-H activation
  • Carbene ligands
  • Hydrides
  • Iridium

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