A First Cyclodextrin-Transition Metal Coordination Polymer

Heng Xu; Sabina Rodríguez-Hermida; Javier Pérez-Carvajal; Jordi Juanhuix; Inhar Imaz; Daniel Maspoch

doi:10.1021/acs.cgd.6b01115

A First Cyclodextrin-Transition Metal Coordination Polymer

Heng Xu, Sabina Rodríguez-Hermida, Javier Pérez-Carvajal, Jordi Juanhuix, Inhar Imaz, Daniel Maspoch

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23 Citations (Scopus)

Abstract

© 2016 American Chemical Society. The synthesis, X-ray crystallographic structure, and water uptake measurements of the first coordination polymer made of a cyclodextrin and a transition metal ion (in this case, Cu2+) are shown. This coordination polymer is made by connecting paddle-wheel Cu2+ units through a γ-cyclodextrin functionalized with eight carboxylate groups, is stable in water, and shows selective water-induced reversible structural transformations.

Original language	English
Pages (from-to)	5598-5602
Journal	Crystal Growth and Design
Volume	16
Issue number	10
DOIs	https://doi.org/10.1021/acs.cgd.6b01115
Publication status	Published - 5 Oct 2016

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AU - Rodríguez-Hermida, Sabina

AU - Pérez-Carvajal, Javier

AU - Juanhuix, Jordi

AU - Imaz, Inhar

AU - Maspoch, Daniel

PY - 2016/10/5

Y1 - 2016/10/5

N2 - © 2016 American Chemical Society. The synthesis, X-ray crystallographic structure, and water uptake measurements of the first coordination polymer made of a cyclodextrin and a transition metal ion (in this case, Cu2+) are shown. This coordination polymer is made by connecting paddle-wheel Cu2+ units through a γ-cyclodextrin functionalized with eight carboxylate groups, is stable in water, and shows selective water-induced reversible structural transformations.

AB - © 2016 American Chemical Society. The synthesis, X-ray crystallographic structure, and water uptake measurements of the first coordination polymer made of a cyclodextrin and a transition metal ion (in this case, Cu2+) are shown. This coordination polymer is made by connecting paddle-wheel Cu2+ units through a γ-cyclodextrin functionalized with eight carboxylate groups, is stable in water, and shows selective water-induced reversible structural transformations.

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DO - 10.1021/acs.cgd.6b01115

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VL - 16

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JO - Crystal Growth and Design

JF - Crystal Growth and Design

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A First Cyclodextrin-Transition Metal Coordination Polymer

Abstract

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