A fast photometric titration for the standardization of dithizone solutions

S. Alegret; M. Blanco; J. M. Paulís

doi:10.1016/S0003-2670(00)82963-3

A fast photometric titration for the standardization of dithizone solutions

S. Alegret, M. Blanco, J. M. Paulís

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

A simple method is reported for standardizing 10-5-10-4 M dithizone solutions for titrimetric analysis. Dithizone in an anhydrous acetic acid/chloroform (4% v/v) medium is titrated with 2 × 10-4 M mercury(II) acetate in the same medium. The titratioin takes only a few minutes. The accuracy (+0.2%) and precision (r.s.d. = 0.7%) achieved are similar to those obtained by the classical extractive titration with silver(I). © 1985.

Original language	English
Pages (from-to)	285-289
Journal	Analytica Chimica Acta
Volume	177
Issue number	C
DOIs	https://doi.org/10.1016/S0003-2670(00)82963-3
Publication status	Published - 1 Jan 1985

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title = "A fast photometric titration for the standardization of dithizone solutions",

abstract = "A simple method is reported for standardizing 10-5-10-4 M dithizone solutions for titrimetric analysis. Dithizone in an anhydrous acetic acid/chloroform (4\% v/v) medium is titrated with 2 × 10-4 M mercury(II) acetate in the same medium. The titratioin takes only a few minutes. The accuracy (+0.2\%) and precision (r.s.d. = 0.7\%) achieved are similar to those obtained by the classical extractive titration with silver(I). {\textcopyright} 1985.",

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T1 - A fast photometric titration for the standardization of dithizone solutions

AU - Alegret, S.

AU - Blanco, M.

AU - Paulís, J. M.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - A simple method is reported for standardizing 10-5-10-4 M dithizone solutions for titrimetric analysis. Dithizone in an anhydrous acetic acid/chloroform (4% v/v) medium is titrated with 2 × 10-4 M mercury(II) acetate in the same medium. The titratioin takes only a few minutes. The accuracy (+0.2%) and precision (r.s.d. = 0.7%) achieved are similar to those obtained by the classical extractive titration with silver(I). © 1985.

AB - A simple method is reported for standardizing 10-5-10-4 M dithizone solutions for titrimetric analysis. Dithizone in an anhydrous acetic acid/chloroform (4% v/v) medium is titrated with 2 × 10-4 M mercury(II) acetate in the same medium. The titratioin takes only a few minutes. The accuracy (+0.2%) and precision (r.s.d. = 0.7%) achieved are similar to those obtained by the classical extractive titration with silver(I). © 1985.

UR - https://www.scopus.com/pages/publications/6744231742

U2 - 10.1016/S0003-2670(00)82963-3

DO - 10.1016/S0003-2670(00)82963-3

M3 - Article

SN - 0003-2670

VL - 177

SP - 285

EP - 289

JO - Analytica Chimica Acta

JF - Analytica Chimica Acta

IS - C

ER -

A fast photometric titration for the standardization of dithizone solutions

Abstract

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