A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid

Ricardo Rodriguez, David Gau, Thibault Troadec, Nathalie Saffon-Merceron, Vicenç Branchadell, Antoine Baceiredo, Tsuyoshi Kato

Research output: Contribution to journalArticleResearchpeer-review

44 Citations (Scopus)

Abstract

A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Original languageEnglish
Pages (from-to)8980-8983
JournalAngewandte Chemie - International Edition
Volume52
Issue number34
DOIs
Publication statusPublished - 19 Aug 2013

Keywords

  • phosphorus
  • silanoic acid
  • silanones
  • silicon
  • silylene

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