A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid

Ricardo Rodriguez; David Gau; Thibault Troadec; Nathalie Saffon-Merceron; Vicenç Branchadell; Antoine Baceiredo; Tsuyoshi Kato

doi:10.1002/anie.201304482

A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid

Ricardo Rodriguez, David Gau, Thibault Troadec, Nathalie Saffon-Merceron, Vicenç Branchadell, Antoine Baceiredo, Tsuyoshi Kato

Research output: Contribution to journal › Article › Research › peer-review

44 Citations (Scopus)

Abstract

A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	8980-8983
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	34
DOIs	https://doi.org/10.1002/anie.201304482
Publication status	Published - 19 Aug 2013

Keywords

phosphorus
silanoic acid
silanones
silicon
silylene

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10.1002/anie.201304482

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title = "A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid",

abstract = "A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid. Copyright {\textcopyright} 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

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A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid. / Rodriguez, Ricardo; Gau, David; Troadec, Thibault; Saffon-Merceron, Nathalie; Branchadell, Vicenç; Baceiredo, Antoine; Kato, Tsuyoshi.

In: Angewandte Chemie - International Edition, Vol. 52, No. 34, 19.08.2013, p. 8980-8983.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid

AU - Rodriguez, Ricardo

AU - Gau, David

AU - Troadec, Thibault

AU - Saffon-Merceron, Nathalie

AU - Branchadell, Vicenç

AU - Baceiredo, Antoine

AU - Kato, Tsuyoshi

PY - 2013/8/19

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AB - A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - phosphorus

KW - silanoic acid

KW - silanones

KW - silicon

KW - silylene

U2 - 10.1002/anie.201304482

DO - 10.1002/anie.201304482

M3 - Article

VL - 52

SP - 8980

EP - 8983

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 34

ER -

A base-stabilized sila-β-lactone and a donor/acceptor-stabilized silanoic acid

Abstract

Keywords

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