5-phenylazo-8-aminoquinoline as a sensitive reagent for the extraction-spectrophotometric determination of palladium(II)

M. Blanco; S. Maspoch

doi:10.1007/BF01202674

5-phenylazo-8-aminoquinoline as a sensitive reagent for the extraction-spectrophotometric determination of palladium(II)

M. Blanco, S. Maspoch

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Abstract

The spectrophotometric determination of palladium(II) with 5-phenylazo-8-aminoquinoline (PAQ) is described. The method involves the formation of a Pd-APQ complex in dilute HCl solutions and the conversion of this complex into Pd(PAQ)2 by addition of NaOH. This latter complex is extracted into methyl isobutyl ketone and the absorbance is measured at 620 nm. The molar absorptivity is 7.9×104l·mole-1·cm-1. The method is applied to the determination of Pd(II) in catalysts. © 1983 Springer-Verlag.

Original language	English
Pages (from-to)	11-20
Journal	Mikrochimica Acta
Volume	81
Issue number	1-2
DOIs	https://doi.org/10.1007/BF01202674
Publication status	Published - 1 Jan 1983

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10.1007/BF01202674

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title = "5-phenylazo-8-aminoquinoline as a sensitive reagent for the extraction-spectrophotometric determination of palladium(II)",

abstract = "The spectrophotometric determination of palladium(II) with 5-phenylazo-8-aminoquinoline (PAQ) is described. The method involves the formation of a Pd-APQ complex in dilute HCl solutions and the conversion of this complex into Pd(PAQ)2 by addition of NaOH. This latter complex is extracted into methyl isobutyl ketone and the absorbance is measured at 620 nm. The molar absorptivity is 7.9×104l·mole-1·cm-1. The method is applied to the determination of Pd(II) in catalysts. {\textcopyright} 1983 Springer-Verlag.",

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T1 - 5-phenylazo-8-aminoquinoline as a sensitive reagent for the extraction-spectrophotometric determination of palladium(II)

AU - Blanco, M.

AU - Maspoch, S.

PY - 1983/1/1

Y1 - 1983/1/1

N2 - The spectrophotometric determination of palladium(II) with 5-phenylazo-8-aminoquinoline (PAQ) is described. The method involves the formation of a Pd-APQ complex in dilute HCl solutions and the conversion of this complex into Pd(PAQ)2 by addition of NaOH. This latter complex is extracted into methyl isobutyl ketone and the absorbance is measured at 620 nm. The molar absorptivity is 7.9×104l·mole-1·cm-1. The method is applied to the determination of Pd(II) in catalysts. © 1983 Springer-Verlag.

AB - The spectrophotometric determination of palladium(II) with 5-phenylazo-8-aminoquinoline (PAQ) is described. The method involves the formation of a Pd-APQ complex in dilute HCl solutions and the conversion of this complex into Pd(PAQ)2 by addition of NaOH. This latter complex is extracted into methyl isobutyl ketone and the absorbance is measured at 620 nm. The molar absorptivity is 7.9×104l·mole-1·cm-1. The method is applied to the determination of Pd(II) in catalysts. © 1983 Springer-Verlag.

U2 - 10.1007/BF01202674

DO - 10.1007/BF01202674

M3 - Article

VL - 81

SP - 11

EP - 20

IS - 1-2

ER -

5-phenylazo-8-aminoquinoline as a sensitive reagent for the extraction-spectrophotometric determination of palladium(II)

Abstract

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