5-Methylene-2(5H)-furanone in Diels-Alder reactions with cyclic dienes: endo/exo selectivity

Daniel Alonzo, Vicen Branchadell, Josep Font, Antonio Oliva, Rosa M. Ortuño, Francisco Sánchez-Ferrando

Research output: Contribution to journalArticleResearchpeer-review

14 Citations (Scopus)

Abstract

Endo/exo selectivity in the reactions of 5-methylene-2(5H)-furanone, 1, with cyclic dienes has been investigated. Both the kinetic and theoretical studies of the cycloaddition between 1 and cyclopentadiene have permitted to explain the observed selectivity as a direct consequence of a kinetic control over the process. © 1990.
Original languageEnglish
Pages (from-to)4371-4378
JournalTetrahedron
Volume46
Issue number12
DOIs
Publication statusPublished - 1 Jan 1990

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