5-Methylene-2(5H)-furanone in Diels-Alder reactions with cyclic dienes: endo/exo selectivity

Daniel Alonzo; Vicen Branchadell; Josep Font; Antonio Oliva; Rosa M. Ortuño; Francisco Sánchez-Ferrando

doi:10.1016/S0040-4020(01)86771-5

5-Methylene-2(5H)-furanone in Diels-Alder reactions with cyclic dienes: endo/exo selectivity

Daniel Alonzo, Vicen Branchadell, Josep Font, Antonio Oliva, Rosa M. Ortuño, Francisco Sánchez-Ferrando

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

Endo/exo selectivity in the reactions of 5-methylene-2(5H)-furanone, 1, with cyclic dienes has been investigated. Both the kinetic and theoretical studies of the cycloaddition between 1 and cyclopentadiene have permitted to explain the observed selectivity as a direct consequence of a kinetic control over the process. © 1990.

Original language	English
Pages (from-to)	4371-4378
Journal	Tetrahedron
Volume	46
Issue number	12
DOIs	https://doi.org/10.1016/S0040-4020(01)86771-5
Publication status	Published - 1 Jan 1990

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title = "5-Methylene-2(5H)-furanone in Diels-Alder reactions with cyclic dienes: endo/exo selectivity",

abstract = "Endo/exo selectivity in the reactions of 5-methylene-2(5H)-furanone, 1, with cyclic dienes has been investigated. Both the kinetic and theoretical studies of the cycloaddition between 1 and cyclopentadiene have permitted to explain the observed selectivity as a direct consequence of a kinetic control over the process. {\textcopyright} 1990.",

author = "Daniel Alonzo and Vicen Branchadell and Josep Font and Antonio Oliva and Ortu{\~n}o, {Rosa M.} and Francisco S{\'a}nchez-Ferrando",

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T1 - 5-Methylene-2(5H)-furanone in Diels-Alder reactions with cyclic dienes: endo/exo selectivity

AU - Alonzo, Daniel

AU - Branchadell, Vicen

AU - Font, Josep

AU - Oliva, Antonio

AU - Ortuño, Rosa M.

AU - Sánchez-Ferrando, Francisco

PY - 1990/1/1

Y1 - 1990/1/1

N2 - Endo/exo selectivity in the reactions of 5-methylene-2(5H)-furanone, 1, with cyclic dienes has been investigated. Both the kinetic and theoretical studies of the cycloaddition between 1 and cyclopentadiene have permitted to explain the observed selectivity as a direct consequence of a kinetic control over the process. © 1990.

AB - Endo/exo selectivity in the reactions of 5-methylene-2(5H)-furanone, 1, with cyclic dienes has been investigated. Both the kinetic and theoretical studies of the cycloaddition between 1 and cyclopentadiene have permitted to explain the observed selectivity as a direct consequence of a kinetic control over the process. © 1990.

U2 - 10.1016/S0040-4020(01)86771-5

DO - 10.1016/S0040-4020(01)86771-5

M3 - Article

SN - 0040-4020

VL - 46

SP - 4371

EP - 4378

JO - Tetrahedron

JF - Tetrahedron

IS - 12

ER -

5-Methylene-2(5H)-furanone in Diels-Alder reactions with cyclic dienes: endo/exo selectivity

Abstract

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