2,2′-isopropylidenebis[(4R)-(1-adamantyl)-2-oxazoline] (Adam-Box). A new enantiopure C2-symmetrical ligand: Enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations

Jaume Clariana; Josep Comelles; Marcial Moreno-Mañas; Adelina Vallribera

doi:10.1016/S0957-4166(02)00404-4

2,2′-isopropylidenebis[(4R)-(1-adamantyl)-2-oxazoline] (Adam-Box). A new enantiopure C₂-symmetrical ligand: Enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations

Jaume Clariana, Josep Comelles, Marcial Moreno-Mañas, Adelina Vallribera

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

34 Citations (Scopus)

Abstract

The title bisoxazoline (Box) featuring two adamantane skeletons (Adam-Box) is a ligand of (R,R)-configuration, which combined with copper sources makes excellent catalysts for enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations. © 2002 Published by Elsevier Science Ltd.

Original language	English
Pages (from-to)	1551-1554
Journal	Tetrahedron Asymmetry
Volume	13
Issue number	14
DOIs	https://doi.org/10.1016/S0957-4166(02)00404-4
Publication status	Published - 1 Aug 2002

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10.1016/S0957-4166(02)00404-4

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title = "2,2′-isopropylidenebis[(4R)-(1-adamantyl)-2-oxazoline] (Adam-Box). A new enantiopure C2-symmetrical ligand: Enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations",

abstract = "The title bisoxazoline (Box) featuring two adamantane skeletons (Adam-Box) is a ligand of (R,R)-configuration, which combined with copper sources makes excellent catalysts for enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations. {\textcopyright} 2002 Published by Elsevier Science Ltd.",

author = "Jaume Clariana and Josep Comelles and Marcial Moreno-Ma{\~n}as and Adelina Vallribera",

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2,2′-isopropylidenebis[(4R)-(1-adamantyl)-2-oxazoline] (Adam-Box). A new enantiopure C₂-symmetrical ligand: Enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations. / Clariana, Jaume; Comelles, Josep; Moreno-Mañas, Marcial; Vallribera, Adelina.

In: Tetrahedron Asymmetry, Vol. 13, No. 14, 01.08.2002, p. 1551-1554.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - 2,2′-isopropylidenebis[(4R)-(1-adamantyl)-2-oxazoline] (Adam-Box). A new enantiopure C2-symmetrical ligand: Enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations

AU - Clariana, Jaume

AU - Comelles, Josep

AU - Moreno-Mañas, Marcial

AU - Vallribera, Adelina

PY - 2002/8/1

Y1 - 2002/8/1

N2 - The title bisoxazoline (Box) featuring two adamantane skeletons (Adam-Box) is a ligand of (R,R)-configuration, which combined with copper sources makes excellent catalysts for enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations. © 2002 Published by Elsevier Science Ltd.

AB - The title bisoxazoline (Box) featuring two adamantane skeletons (Adam-Box) is a ligand of (R,R)-configuration, which combined with copper sources makes excellent catalysts for enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations. © 2002 Published by Elsevier Science Ltd.

U2 - 10.1016/S0957-4166(02)00404-4

DO - 10.1016/S0957-4166(02)00404-4

M3 - Article

VL - 13

SP - 1551

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IS - 14

ER -

2,2′-isopropylidenebis[(4R)-(1-adamantyl)-2-oxazoline] (Adam-Box). A new enantiopure C2-symmetrical ligand: Enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations

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2,2′-isopropylidenebis[(4R)-(1-adamantyl)-2-oxazoline] (Adam-Box). A new enantiopure C₂-symmetrical ligand: Enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations