15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes. A review

Marcial Moreno-Mañas, Roser Pleixats, Anna Roglans, Rosa M. Sebastián, Adelina Vallribera

Research output: Contribution to journalReview articleResearchpeer-review

33 Citations (Scopus)

Abstract

(E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.
Original languageEnglish
Pages (from-to)109-129
JournalArkivoc
Volume2004
Issue number4
Publication statusPublished - 1 Jan 2004

Keywords

  • Alkene ligands
  • Catalysis
  • Heterocycles
  • Macrocycles
  • Olefin complexes

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