15-Membered triolefinic macrocycles as stabilizers of palladium(0) nanoparticles

Anna Serra-Muns, Roger Soler, Elena Badetti, Paula De Mendoza, Marcial Moreno-Mañas, Roser Pleixats, Rosa M. Sebastián, Adelina Vallribera

Research output: Contribution to journalArticleResearchpeer-review

35 Citations (Scopus)

Abstract

15-Membered triolefinic macrocycles form complexes with palladium(0). However, metal nanoparticles are formed instead of discrete complexes if substituents provided with the ability to stabilize nanoparticles are incorporated into the structure of the macrocycle. Ancillary substituents include fluorous and polyoxyethylenated chains. The role of initial organometallic coordination in the early steps of nanoparticle formation is underlined. © the Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2006.
Original languageEnglish
Pages (from-to)1584-1594
JournalNew Journal of Chemistry
Volume30
Issue number11
DOIs
Publication statusPublished - 14 Nov 2006

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