1,3-dipolar cycloadditions of cyclic nitrones to γ-bromo α,β- unsaturated esters and lactones

Pedro De March, Marta Figueredo, Josep Font, Antonio Salgado

Research output: Contribution to journalArticleResearchpeer-review

9 Citations (Scopus)

Abstract

The 1,3-dipolar cycloaddition of cyclic nitrones to several γ-bromo α,β-unsaturated esters and lactones has been studied. All the reactions have shown high stereoselectivity, with a predominance of the endo or exo transition state for the trans or cis dipolarophiles, respectively.
Original languageEnglish
Pages (from-to)6947-6956
JournalTetrahedron
Volume54
Issue number24
DOIs
Publication statusPublished - 11 Jun 1998

Keywords

  • Cycloaddition
  • Nitrones
  • Olefins
  • Stereoselection

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