α,α′-Bis(trifluoromethyl)-9,10-anthracenedimethanol: Enantioselective synthesis and bidentate complexes with benzenedimethanols

Carla Estivill; Petko M. Ivanov; Marta Pomares; Marta Sánchez-Arís; Albert Virgili

doi:10.1016/j.tetasy.2004.03.019

α,α′-Bis(trifluoromethyl)-9,10-anthracenedimethanol: Enantioselective synthesis and bidentate complexes with benzenedimethanols

Carla Estivill, Petko M. Ivanov, Marta Pomares, Marta Sánchez-Arís, Albert Virgili

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

7 Citations (Scopus)

Abstract

α,α′-Bis(trifluoromethyl)-9, 10-anthracenedimethanol was prepared by a one pot stereoselective double reduction in good yield and excellent enantiomeric excess. We examined the association with ortho- and meta-benzenedimethanol showing bidentate complexes stable enough to be studied by low temperature NMR. Molecular modeling helped us to propose an association complex. © 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1431-1436
Journal	Tetrahedron Asymmetry
Volume	15
Issue number	9
DOIs	https://doi.org/10.1016/j.tetasy.2004.03.019
Publication status	Published - 10 May 2004

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10.1016/j.tetasy.2004.03.019

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title = "α,α′-Bis(trifluoromethyl)-9,10-anthracenedimethanol: Enantioselective synthesis and bidentate complexes with benzenedimethanols",

abstract = "α,α′-Bis(trifluoromethyl)-9, 10-anthracenedimethanol was prepared by a one pot stereoselective double reduction in good yield and excellent enantiomeric excess. We examined the association with ortho- and meta-benzenedimethanol showing bidentate complexes stable enough to be studied by low temperature NMR. Molecular modeling helped us to propose an association complex. {\textcopyright} 2004 Elsevier Ltd. All rights reserved.",

author = "Carla Estivill and Ivanov, {Petko M.} and Marta Pomares and Marta S{\'a}nchez-Ar{\'i}s and Albert Virgili",

year = "2004",

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α,α′-Bis(trifluoromethyl)-9,10-anthracenedimethanol: Enantioselective synthesis and bidentate complexes with benzenedimethanols. / Estivill, Carla; Ivanov, Petko M.; Pomares, Marta; Sánchez-Arís, Marta; Virgili, Albert.

In: Tetrahedron Asymmetry, Vol. 15, No. 9, 10.05.2004, p. 1431-1436.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - α,α′-Bis(trifluoromethyl)-9,10-anthracenedimethanol: Enantioselective synthesis and bidentate complexes with benzenedimethanols

AU - Estivill, Carla

AU - Ivanov, Petko M.

AU - Pomares, Marta

AU - Sánchez-Arís, Marta

AU - Virgili, Albert

PY - 2004/5/10

Y1 - 2004/5/10

N2 - α,α′-Bis(trifluoromethyl)-9, 10-anthracenedimethanol was prepared by a one pot stereoselective double reduction in good yield and excellent enantiomeric excess. We examined the association with ortho- and meta-benzenedimethanol showing bidentate complexes stable enough to be studied by low temperature NMR. Molecular modeling helped us to propose an association complex. © 2004 Elsevier Ltd. All rights reserved.

AB - α,α′-Bis(trifluoromethyl)-9, 10-anthracenedimethanol was prepared by a one pot stereoselective double reduction in good yield and excellent enantiomeric excess. We examined the association with ortho- and meta-benzenedimethanol showing bidentate complexes stable enough to be studied by low temperature NMR. Molecular modeling helped us to propose an association complex. © 2004 Elsevier Ltd. All rights reserved.

U2 - 10.1016/j.tetasy.2004.03.019

DO - 10.1016/j.tetasy.2004.03.019

M3 - Article

VL - 15

SP - 1431

EP - 1436

IS - 9

ER -

α,α′-Bis(trifluoromethyl)-9,10-anthracenedimethanol: Enantioselective synthesis and bidentate complexes with benzenedimethanols

Abstract

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