In this project we will synthesize different class of ligands which will be coordinated to transition metals: amphiphilic phosphines, water-soluble carboxylates and thiolates. These complexes will be tested as catalysts, in particular in two-phase catalytic reactions. We will start the synthesis of polydentate ligands by coupling glycerol with other substrates, specially N-donors in order to be useful in asymmetric catalysis. Amphiphilic ligands prepared by our group will be studied as a coordinating agents to \super 99m\nosuper Tc and the obtained complexes will be tested as radiopharmaceuticals.
|Effective start/end date||1/12/97 → 1/12/00|