@article{abe3625106554b9282b22f958621e2fd,
title = "X-ray, IR and 1H-NMR structural and conformational study of highly congested 2-alkyl-1,3-diols and of 3-(1-adamantyl)pentane-2,4-dione",
abstract = "Configuration of meso diols produced by LiA1H4 reduction of symmetric α-(1-adamantyl)-β-diketones has been determined by X-ray diffraction. Large C-C distances and C-C-C angles have been measured for these strained molecules. Most of the studied 1,3-diols, both meso and d,1, exist in solution in conformations possesing intramolecular hydrogen bond. The conformations of two diols were also studied in the crystal phase. {\textcopyright} 1992.",
keywords = "Configuration determination, conformational analysis, hydrogen bond, infrared and 1H-NMR spectroscopy, pseudoasymmetric atoms, X-ray diffraction",
author = "M. Moreno-Ma{\~n}as and Piniella, {J. F.} and A. Alvarez-Larena and N. Galvez and Lloris, {M. E.} and J. Marquet and Siani, {A. C.} and G. Germain",
year = "1992",
month = jan,
day = "1",
doi = "10.1016/S0040-4020(01)88499-4",
language = "English",
volume = "48",
pages = "3611--3622",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "17",
}