Water Oxidation

R. Bofill; J. García-Antón; L. Escriche; X. Sala; A. Llobet

doi:10.1016/B978-0-08-097774-4.00821-4

Water Oxidation

R. Bofill, J. García-Antón, L. Escriche, X. Sala, A. Llobet

Departament de Química

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8 Cites (Scopus)

Resum

The replacement of fossil fuels by hydrogen generated by water splitting with sunlight is a very attractive solution to today's energy problem. In order to develop a practical technology based on these elements, robust and efficient water oxidation catalysts (WOCs) need to be developed. The molecular complexity involved in water oxidation is such that sophisticated catalysts consisting of transition metal complexes - which can access low-energy reaction pathways - are considered essential. Complexes based on first row transition metals such as Mn, Co, and Fe have been reported recently, in addition to those of the second row Ru and third row Ir, which had been previously described. In the present chapter, a comprehensive view of these WOCs and their performance is offered. © 2013 Elsevier Ltd. All rights reserved.

Idioma original	Anglès
Títol de la publicació	Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications
Editors	J. A. McClevert, T.J. Meyer.
Lloc de publicació	Amsterdam (NL)
Editor	Elsevier
Pàgines	505-523
Nombre de pàgines	18
Volum	8
Edició	1
ISBN (imprès)	9780080965291
DOIs	https://doi.org/10.1016/B978-0-08-097774-4.00821-4
Estat de la publicació	Publicada - 1 d’ag. 2013

Sèrie de publicacions

Nom	Comprehensive Inorganic Chemistry II

SDG de les Nacions Unides

Aquest resultat contribueix als següents objectius de desenvolupament sostenible.

Accés al document

10.1016/B978-0-08-097774-4.00821-4

Com citar-ho

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abstract = "The replacement of fossil fuels by hydrogen generated by water splitting with sunlight is a very attractive solution to today's energy problem. In order to develop a practical technology based on these elements, robust and efficient water oxidation catalysts (WOCs) need to be developed. The molecular complexity involved in water oxidation is such that sophisticated catalysts consisting of transition metal complexes - which can access low-energy reaction pathways - are considered essential. Complexes based on first row transition metals such as Mn, Co, and Fe have been reported recently, in addition to those of the second row Ru and third row Ir, which had been previously described. In the present chapter, a comprehensive view of these WOCs and their performance is offered. {\textcopyright} 2013 Elsevier Ltd. All rights reserved.",

keywords = "Artificial photosynthesis, Energy conversion schemes, High oxidation states, O-O bond formation, Photosynthesis, Reaction mechanism, Redox catalysis, Transition metals, Water oxidation, Water splitting",

author = "R. Bofill and J. Garc{\'i}a-Ant{\'o}n and L. Escriche and X. Sala and A. Llobet",

year = "2013",

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Water Oxidation. / Bofill, R.; García-Antón, J.; Escriche, L. et al.
Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications. ed. / J. A. McClevert; T.J. Meyer. Vol. 8 1. ed. Amsterdam (NL): Elsevier, 2013. pàg. 505-523 (Comprehensive Inorganic Chemistry II).

Producció científica: Capítol de llibre › Capítol › Recerca › Avaluat per experts

TY - CHAP

T1 - Water Oxidation

AU - Bofill, R.

AU - García-Antón, J.

AU - Escriche, L.

AU - Sala, X.

AU - Llobet, A.

PY - 2013/8/1

Y1 - 2013/8/1

N2 - The replacement of fossil fuels by hydrogen generated by water splitting with sunlight is a very attractive solution to today's energy problem. In order to develop a practical technology based on these elements, robust and efficient water oxidation catalysts (WOCs) need to be developed. The molecular complexity involved in water oxidation is such that sophisticated catalysts consisting of transition metal complexes - which can access low-energy reaction pathways - are considered essential. Complexes based on first row transition metals such as Mn, Co, and Fe have been reported recently, in addition to those of the second row Ru and third row Ir, which had been previously described. In the present chapter, a comprehensive view of these WOCs and their performance is offered. © 2013 Elsevier Ltd. All rights reserved.

AB - The replacement of fossil fuels by hydrogen generated by water splitting with sunlight is a very attractive solution to today's energy problem. In order to develop a practical technology based on these elements, robust and efficient water oxidation catalysts (WOCs) need to be developed. The molecular complexity involved in water oxidation is such that sophisticated catalysts consisting of transition metal complexes - which can access low-energy reaction pathways - are considered essential. Complexes based on first row transition metals such as Mn, Co, and Fe have been reported recently, in addition to those of the second row Ru and third row Ir, which had been previously described. In the present chapter, a comprehensive view of these WOCs and their performance is offered. © 2013 Elsevier Ltd. All rights reserved.

KW - Artificial photosynthesis

KW - Energy conversion schemes

KW - High oxidation states

KW - O-O bond formation

KW - Photosynthesis

KW - Reaction mechanism

KW - Redox catalysis

KW - Transition metals

KW - Water oxidation

KW - Water splitting

U2 - 10.1016/B978-0-08-097774-4.00821-4

DO - 10.1016/B978-0-08-097774-4.00821-4

M3 - Chapter

SN - 9780080965291

VL - 8

T3 - Comprehensive Inorganic Chemistry II

SP - 505

EP - 523

BT - Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications

A2 - J. A. McClevert, null

A2 - T.J. Meyer., null

PB - Elsevier

CY - Amsterdam (NL)

ER -

Water Oxidation

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