Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]

Angel Alvarez-Larena; José L. Briansó; Juan F. Piniella; Joan Farran; Juan M. Manríquez; Ivonne Chávez; Beatriz Oelckers; Elies Molins; Carles Miravitlles

doi:10.1107/S0108270196008037

Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]

Angel Alvarez-Larena^*, José L. Briansó, Juan F. Piniella, Joan Farran, Juan M. Manríquez, Ivonne Chávez, Beatriz Oelckers, Elies Molins, Carles Miravitlles

^*Autor corresponent d’aquest treball

Departament de Geologia

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

5 Cites (Scopus)

Resum

The title compound, [2(1,2,3,3a,6a-η)-1,4-dihydropentalenyl][μ-(1,2,3,3a,6a-η:3a,4,5,6, 6a-η)pentalene]-[1(η5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H 15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas the bridge bond is longer; there are two significantly different Fe - C distances, i.e. a mean value of 2.121 (3) Å for the Fe - Cbridge distances and a mean value of 2.028 (3) Å for the distances from the Fe atoms to all other C atoms. In the terminal pentalene ligand, the C - C and C - Fe distances in the ring bonded to the Fe atom are all similar.

Idioma original	Anglès
Pàgines (de-a)	2754-2757
Nombre de pàgines	4
Revista	Acta Crystallographica Section C: Crystal Structure Communications
Volum	52
Número	11
DOIs	https://doi.org/10.1107/S0108270196008037 https://doi.org/10.1107/S0108270196008037
Estat de la publicació	Publicada - 15 de nov. 1996

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CCDC 128164: Experimental Crystal Structure Determination
Álvarez Larena, A. (Creador), Briansó, J. L. (Col·laborador), Piniella, J. F. (Creador), Farran, J. (Creador), Manríquez, J. M. (Col·laborador), Chávez, I. (Col·laborador), Oelckers, B. (Creador), Molins, E. (Creador) & Miravitlles, C. (Creador), Cambridge Crystallographic Data Centre, 16 de des. 1996
DOI: 10.5517/cc49cb3, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc49cb3&sid=DataCite
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@article{c41534a10e0d4470b9cee2e286c0fba7,

title = "Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)] ",

abstract = "The title compound, [2(1,2,3,3a,6a-η)-1,4-dihydropentalenyl][μ-(1,2,3,3a,6a-η:3a,4,5,6, 6a-η)pentalene]-[1(η5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H 15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas the bridge bond is longer; there are two significantly different Fe - C distances, i.e. a mean value of 2.121 (3) {\AA} for the Fe - Cbridge distances and a mean value of 2.028 (3) {\AA} for the distances from the Fe atoms to all other C atoms. In the terminal pentalene ligand, the C - C and C - Fe distances in the ring bonded to the Fe atom are all similar.",

author = "Angel Alvarez-Larena and Brians{\'o}, {Jos{\'e} L.} and Piniella, {Juan F.} and Joan Farran and Manr{\'i}quez, {Juan M.} and Ivonne Ch{\'a}vez and Beatriz Oelckers and Elies Molins and Carles Miravitlles",

year = "1996",

month = nov,

day = "15",

doi = "10.1107/S0108270196008037",

language = "English",

volume = "52",

pages = "2754--2757",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]

AU - Alvarez-Larena, Angel

AU - Briansó, José L.

AU - Piniella, Juan F.

AU - Farran, Joan

AU - Manríquez, Juan M.

AU - Chávez, Ivonne

AU - Oelckers, Beatriz

AU - Molins, Elies

AU - Miravitlles, Carles

PY - 1996/11/15

Y1 - 1996/11/15

N2 - The title compound, [2(1,2,3,3a,6a-η)-1,4-dihydropentalenyl][μ-(1,2,3,3a,6a-η:3a,4,5,6, 6a-η)pentalene]-[1(η5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H 15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas the bridge bond is longer; there are two significantly different Fe - C distances, i.e. a mean value of 2.121 (3) Å for the Fe - Cbridge distances and a mean value of 2.028 (3) Å for the distances from the Fe atoms to all other C atoms. In the terminal pentalene ligand, the C - C and C - Fe distances in the ring bonded to the Fe atom are all similar.

AB - The title compound, [2(1,2,3,3a,6a-η)-1,4-dihydropentalenyl][μ-(1,2,3,3a,6a-η:3a,4,5,6, 6a-η)pentalene]-[1(η5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H 15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas the bridge bond is longer; there are two significantly different Fe - C distances, i.e. a mean value of 2.121 (3) Å for the Fe - Cbridge distances and a mean value of 2.028 (3) Å for the distances from the Fe atoms to all other C atoms. In the terminal pentalene ligand, the C - C and C - Fe distances in the ring bonded to the Fe atom are all similar.

UR - http://www.scopus.com/inward/record.url?scp=0030286535&partnerID=8YFLogxK

U2 - 10.1107/S0108270196008037

DO - 10.1107/S0108270196008037

M3 - Article

SN - 0108-2701

VL - 52

SP - 2754

EP - 2757

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 11

ER -

Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]

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CCDC 128164: Experimental Crystal Structure Determination

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