The use of perdeuterio 2,2,2,-trifluoro-1-(9-Anthryl) ethanol as chiral solvating agent. Chiral induction observed on 1H and 13 C NMR

A. Muñoz; A. Virgili

The use of perdeuterio 2,2,2,-trifluoro-1-(9-Anthryl) ethanol as chiral solvating agent. Chiral induction observed on ¹H and ¹³ C NMR

A. Muñoz, A. Virgili

Departament de Química

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

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Resum

The first chiral solvating agent without NMR signals, the perdeuterio 2,2,2-trifluoro-1-(9-anthryl)ethanol, was tested with several enantiomer mixtures. Its behaviour is similar to that of Pirkle alcohol but improving chiral recognition experiments done by 1H and 13C NMR spectroscopy.

Idioma original	Anglès
Pàgines (de-a)	235-243
Revista	Enantiomer
Volum	6
Número	4
Estat de la publicació	Publicada - 1 de gen. 2001

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https://www.scopus.com/pages/publications/0034753050

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title = "The use of perdeuterio 2,2,2,-trifluoro-1-(9-Anthryl) ethanol as chiral solvating agent. Chiral induction observed on 1H and 13 C NMR",

abstract = "The first chiral solvating agent without NMR signals, the perdeuterio 2,2,2-trifluoro-1-(9-anthryl)ethanol, was tested with several enantiomer mixtures. Its behaviour is similar to that of Pirkle alcohol but improving chiral recognition experiments done by 1H and 13C NMR spectroscopy.",

keywords = "13 C NMR, 1 H NMR, CSA (chiral solvating agent), Enantiodifferentiation, Perdeuterated compounds",

author = "A. Mu{\~n}oz and A. Virgili",

year = "2001",

month = jan,

day = "1",

language = "English",

volume = "6",

pages = "235--243",

journal = "Enantiomer",

issn = "1024-2430",

publisher = "Taylor and Francis Ltd.",

number = "4",

}

TY - JOUR

T1 - The use of perdeuterio 2,2,2,-trifluoro-1-(9-Anthryl) ethanol as chiral solvating agent. Chiral induction observed on 1H and 13 C NMR

AU - Muñoz, A.

AU - Virgili, A.

PY - 2001/1/1

Y1 - 2001/1/1

N2 - The first chiral solvating agent without NMR signals, the perdeuterio 2,2,2-trifluoro-1-(9-anthryl)ethanol, was tested with several enantiomer mixtures. Its behaviour is similar to that of Pirkle alcohol but improving chiral recognition experiments done by 1H and 13C NMR spectroscopy.

AB - The first chiral solvating agent without NMR signals, the perdeuterio 2,2,2-trifluoro-1-(9-anthryl)ethanol, was tested with several enantiomer mixtures. Its behaviour is similar to that of Pirkle alcohol but improving chiral recognition experiments done by 1H and 13C NMR spectroscopy.

KW - 13 C NMR

KW - 1 H NMR

KW - CSA (chiral solvating agent)

KW - Enantiodifferentiation

KW - Perdeuterated compounds

UR - https://www.scopus.com/pages/publications/0034753050

M3 - Article

SN - 1024-2430

VL - 6

SP - 235

EP - 243

JO - Enantiomer

JF - Enantiomer

IS - 4

ER -

The use of perdeuterio 2,2,2,-trifluoro-1-(9-Anthryl) ethanol as chiral solvating agent. Chiral induction observed on 1H and 13 C NMR

Resum

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The use of perdeuterio 2,2,2,-trifluoro-1-(9-Anthryl) ethanol as chiral solvating agent. Chiral induction observed on ¹H and ¹³ C NMR