The silicon effect on the regioselectivity of the Tsuji-Trost reaction. Experimental and theoretical approaches

Vicenç Branchadell; Marcial Moreno-Mañas; Roser Pleixats; Serge Thorimbert; Claude Commandeur; Cécile Boglio; Max Malacria

doi:10.1016/S0022-328X(03)00664-8

The silicon effect on the regioselectivity of the Tsuji-Trost reaction. Experimental and theoretical approaches

Vicenç Branchadell, Marcial Moreno-Mañas, Roser Pleixats, Serge Thorimbert, Claude Commandeur, Cécile Boglio, Max Malacria

Departament de Química

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Regioselectivity of the Tsuji-Trost reaction on allyl acetates and carbonates substituted with silyl groups at the olefinic moiety has been analyzed. Silicon atom in the central carbon atom increases the stability of the intermediate π-allylpalladium cation with respect to the isomeric π-allylpalladium cation featuring the silicon in a terminal carbon atom. © 2003 Elsevier B.V. All rights reserved.

Idioma original	Anglès
Pàgines (de-a)	337-345
Revista	Journal of Organometallic Chemistry
Volum	687
Número	2
DOIs	https://doi.org/10.1016/S0022-328X(03)00664-8
Estat de la publicació	Publicada - 7 de des. 2003

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abstract = "Regioselectivity of the Tsuji-Trost reaction on allyl acetates and carbonates substituted with silyl groups at the olefinic moiety has been analyzed. Silicon atom in the central carbon atom increases the stability of the intermediate π-allylpalladium cation with respect to the isomeric π-allylpalladium cation featuring the silicon in a terminal carbon atom. {\textcopyright} 2003 Elsevier B.V. All rights reserved.",

keywords = "Calculations, Regioselectivity, Silicon effect, Tsuji-Trost reaction",

author = "Vicen{\c c} Branchadell and Marcial Moreno-Ma{\~n}as and Roser Pleixats and Serge Thorimbert and Claude Commandeur and C{\'e}cile Boglio and Max Malacria",

year = "2003",

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doi = "10.1016/S0022-328X(03)00664-8",

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TY - JOUR

T1 - The silicon effect on the regioselectivity of the Tsuji-Trost reaction. Experimental and theoretical approaches

AU - Branchadell, Vicenç

AU - Moreno-Mañas, Marcial

AU - Pleixats, Roser

AU - Thorimbert, Serge

AU - Commandeur, Claude

AU - Boglio, Cécile

AU - Malacria, Max

PY - 2003/12/7

Y1 - 2003/12/7

N2 - Regioselectivity of the Tsuji-Trost reaction on allyl acetates and carbonates substituted with silyl groups at the olefinic moiety has been analyzed. Silicon atom in the central carbon atom increases the stability of the intermediate π-allylpalladium cation with respect to the isomeric π-allylpalladium cation featuring the silicon in a terminal carbon atom. © 2003 Elsevier B.V. All rights reserved.

AB - Regioselectivity of the Tsuji-Trost reaction on allyl acetates and carbonates substituted with silyl groups at the olefinic moiety has been analyzed. Silicon atom in the central carbon atom increases the stability of the intermediate π-allylpalladium cation with respect to the isomeric π-allylpalladium cation featuring the silicon in a terminal carbon atom. © 2003 Elsevier B.V. All rights reserved.

KW - Calculations

KW - Regioselectivity

KW - Silicon effect

KW - Tsuji-Trost reaction

UR - https://www.scopus.com/pages/publications/0344875121

U2 - 10.1016/S0022-328X(03)00664-8

DO - 10.1016/S0022-328X(03)00664-8

M3 - Article

SN - 0022-328X

VL - 687

SP - 337

EP - 345

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

The silicon effect on the regioselectivity of the Tsuji-Trost reaction. Experimental and theoretical approaches

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