The nucleophilic aromatic photosubstitution in photoaffinity labelling. A model study of a cycloheximide derivative.

A. Castelló, J. Marquet, M. Moreno-Mañas, X. Sirera

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Resum

The photoreactions of several 4-nitrocatechol ethers with the relatively hard nucleophile methylamine occurs at the meta position respect to the nitro group. A derivative of the antibiotic cycloheximide carrying a 4-nitrocatechol ether moiety reacts with methylamine affording an in vitro model for photoaffinity labelling. © 1985.
Idioma originalEnglish
Pàgines (de-a)2489-2492
RevistaTetrahedron Letters
Volum26
Número20
DOIs
Estat de la publicacióPublicada - 1 de gen. 1985

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