The CSIC reaction on substrates derived from aldehydes

José L. Marco; Simon T. Ingate; Carlos Jaime; Ivan Beá

doi:10.1016/S0040-4020(00)00124-1

The CSIC reaction on substrates derived from aldehydes

José L. Marco, Simon T. Ingate, Carlos Jaime, Ivan Beá

Departament de Química

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

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Resum

The Carbanion-mediated Sulfonate (Sulfonamide) Intramolecular Cyclization reaction (CSIC reaction) on conveniently functionalized cyanoalkylsulfonates and cyanoalkylsulfonamides derived from aldehydes is possible and gives the new heterocyclic ring systems 5-alkyl-4-amino-5H-1,2- oxathiole 2,2-dioxide and 3-alkyl-5H-4-amino-5-cyano-5H-2,3- dihydroisothiazole 1,1-dioxide in good yield. (C) 2000 Elsevier Science Ltd.

Idioma original	Anglès
Pàgines (de-a)	2523-2531
Revista	Tetrahedron
Volum	56
Número	16
DOIs	https://doi.org/10.1016/S0040-4020(00)00124-1
Estat de la publicació	Publicada - 14 d’abr. 2000

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https://www.scopus.com/pages/publications/0034647063

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title = "The CSIC reaction on substrates derived from aldehydes",

abstract = "The Carbanion-mediated Sulfonate (Sulfonamide) Intramolecular Cyclization reaction (CSIC reaction) on conveniently functionalized cyanoalkylsulfonates and cyanoalkylsulfonamides derived from aldehydes is possible and gives the new heterocyclic ring systems 5-alkyl-4-amino-5H-1,2- oxathiole 2,2-dioxide and 3-alkyl-5H-4-amino-5-cyano-5H-2,3- dihydroisothiazole 1,1-dioxide in good yield. (C) 2000 Elsevier Science Ltd.",

keywords = "Cyanoalkylsulfonamides, Cyanoalkylsulfonates, Non-nucleophilic bases",

author = "Marco, \{Jos{\'e} L.\} and Ingate, \{Simon T.\} and Carlos Jaime and Ivan Be{\'a}",

year = "2000",

month = apr,

day = "14",

doi = "10.1016/S0040-4020(00)00124-1",

language = "English",

volume = "56",

pages = "2523--2531",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "16",

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TY - JOUR

T1 - The CSIC reaction on substrates derived from aldehydes

AU - Marco, José L.

AU - Ingate, Simon T.

AU - Jaime, Carlos

AU - Beá, Ivan

PY - 2000/4/14

Y1 - 2000/4/14

N2 - The Carbanion-mediated Sulfonate (Sulfonamide) Intramolecular Cyclization reaction (CSIC reaction) on conveniently functionalized cyanoalkylsulfonates and cyanoalkylsulfonamides derived from aldehydes is possible and gives the new heterocyclic ring systems 5-alkyl-4-amino-5H-1,2- oxathiole 2,2-dioxide and 3-alkyl-5H-4-amino-5-cyano-5H-2,3- dihydroisothiazole 1,1-dioxide in good yield. (C) 2000 Elsevier Science Ltd.

AB - The Carbanion-mediated Sulfonate (Sulfonamide) Intramolecular Cyclization reaction (CSIC reaction) on conveniently functionalized cyanoalkylsulfonates and cyanoalkylsulfonamides derived from aldehydes is possible and gives the new heterocyclic ring systems 5-alkyl-4-amino-5H-1,2- oxathiole 2,2-dioxide and 3-alkyl-5H-4-amino-5-cyano-5H-2,3- dihydroisothiazole 1,1-dioxide in good yield. (C) 2000 Elsevier Science Ltd.

KW - Cyanoalkylsulfonamides

KW - Cyanoalkylsulfonates

KW - Non-nucleophilic bases

UR - https://www.scopus.com/pages/publications/0034647063

U2 - 10.1016/S0040-4020(00)00124-1

DO - 10.1016/S0040-4020(00)00124-1

M3 - Article

SN - 0040-4020

VL - 56

SP - 2523

EP - 2531

JO - Tetrahedron

JF - Tetrahedron

IS - 16

ER -

The CSIC reaction on substrates derived from aldehydes

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