Synthesis, structure, and dynamic behaviour of transition metal chelate complexes with atropisomeric dithioether ligands

Serafino Gladiali, Davide Fabbri, Làszlò Kollàr, Carmen Claver, Nuria Ruiz, Angel Alvarez-Larena, Joan F. Piniella

Producció científica: Contribució a una revistaArticleRecercaAvaluat per experts

28 Cites (Scopus)

Resum

The preparation and characterization of RhI, PdII, and PtII complexes with chiral C2-symmetrical dithioether ligands derived from 1,1′-binaphthalene-2,2′-dithiol (BINAS) are reported. All complexes are fluxional in solution at room temp. Interconversion between the stereoisomers can take place through conformational equilibration of the chelate ring, and/or inversion of configuration at the stereogenic sulfur. In the solid state the palladium derivative of Me2BINAS shows a twisted chair conformation of the chelate ring, with both methyl groups in equatorial positions.
Idioma originalEnglish
Pàgines (de-a)113-118
RevistaEuropean Journal of Inorganic Chemistry
Número1
Estat de la publicacióPublicada - 1 de gen. 1998

Fingerprint

Navegar pels temes de recerca de 'Synthesis, structure, and dynamic behaviour of transition metal chelate complexes with atropisomeric dithioether ligands'. Junts formen un fingerprint únic.

Com citar-ho