Synthesis of Fe2(CO)6(μ-CRCR′COEtH) complexes (R = R′ = Ph; R = Ph, R′ = Me). New products resulting from the action of [Et3O][BF4] on a mixture of di- and tri-nuclear anionic iron complexes containing a bridging ethene or alkyne ligand

R. Yanez; J. Ros; X. Solans; M. Font-Bardia; R. Mathieu

doi:10.1016/0022-328X(90)85358-6

Synthesis of Fe₂(CO)₆(μ-CRCR′COEtH) complexes (R = R′ = Ph; R = Ph, R′ = Me). New products resulting from the action of [Et₃O][BF₄] on a mixture of di- and tri-nuclear anionic iron complexes containing a bridging ethene or alkyne ligand

R. Yanez, J. Ros, X. Solans, M. Font-Bardia, R. Mathieu

Departament de Química

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5 Cites (Scopus)

Resum

L'acció de [Et3O][BF4] amb la barreja resultant de la reacció dels alquins RCCR′ (R = R′ = Ph; R = Ph, R′ = Me) amb [PPh4][HFe3(CO)11] en THF o acetona bullint condueix a la formació de complexos Fe2(CO)6(μ-CRCR′C(OEt)H) com els productes principals. Per al complex amb R′ = Me, l'estructura de raigs X del complex mostra que la unitat Fe2(CO)6 està unida per un pont mitjançant el fragment orgànic, que és una unió η1η3-a través dels carbonis de la cadena als dos àtoms de ferro i també units a un àtom de ferro a través de l'oxigen del grup etoxi. © 1989.

Idioma original	Anglès
Pàgines (de-a)	169-174
Revista	Journal of Organometallic Chemistry
Volum	388
Número	1-2
DOIs	https://doi.org/10.1016/0022-328X(90)85358-6
Estat de la publicació	Publicada - 15 de maig 1990

Accés al document

10.1016/0022-328X(90)85358-6

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https://www.scopus.com/pages/publications/4244169065

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Yanez, R., Ros, J., Solans, X., Font-Bardia, M., & Mathieu, R. (1990). Synthesis of Fe₂(CO)₆(μ-CRCR′COEtH) complexes (R = R′ = Ph; R = Ph, R′ = Me). New products resulting from the action of [Et₃O][BF₄] on a mixture of di- and tri-nuclear anionic iron complexes containing a bridging ethene or alkyne ligand. Journal of Organometallic Chemistry, 388(1-2), 169-174. https://doi.org/10.1016/0022-328X(90)85358-6

Yanez, R. ; Ros, J. ; Solans, X. et al. / Synthesis of Fe₂(CO)₆(μ-CRCR′COEtH) complexes (R = R′ = Ph; R = Ph, R′ = Me). New products resulting from the action of [Et₃O][BF₄] on a mixture of di- and tri-nuclear anionic iron complexes containing a bridging ethene or alkyne ligand. In: Journal of Organometallic Chemistry. 1990 ; Vol. 388, Núm. 1-2. pàg. 169-174.

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title = "Synthesis of Fe2(CO)6(μ-CRCR′COEtH) complexes (R = R′ = Ph; R = Ph, R′ = Me). New products resulting from the action of [Et3O][BF4] on a mixture of di- and tri-nuclear anionic iron complexes containing a bridging ethene or alkyne ligand",

abstract = "The action of [Et3O][BF4] with the mixture resulting from the reaction of the RCCR′ alkynes (R = R′ = Ph; R = Ph, R′ = Me) with [PPh4][HFe3(CO)11] in boiling THF or acetone leads to the formation of Fe2(CO)6(μ-CRCR′C(OEt)H) complexes as the main products. For the complex with R′ = Me, the X-ray structure of the complex shows that the Fe2(CO)6 unit is bridged by the organic fragment, which is η1η3-bonded through the carbons of the chain to the two iron atoms and also bonded to an iron atom through the oxygen of the ethoxy group. {\textcopyright} 1989.",

author = "R. Yanez and J. Ros and X. Solans and M. Font-Bardia and R. Mathieu",

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doi = "10.1016/0022-328X(90)85358-6",

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Yanez, R, Ros, J, Solans, X, Font-Bardia, M & Mathieu, R 1990, 'Synthesis of Fe₂(CO)₆(μ-CRCR′COEtH) complexes (R = R′ = Ph; R = Ph, R′ = Me). New products resulting from the action of [Et₃O][BF₄] on a mixture of di- and tri-nuclear anionic iron complexes containing a bridging ethene or alkyne ligand', Journal of Organometallic Chemistry, vol. 388, núm. 1-2, pàg. 169-174. https://doi.org/10.1016/0022-328X(90)85358-6

Synthesis of Fe₂(CO)₆(μ-CRCR′COEtH) complexes (R = R′ = Ph; R = Ph, R′ = Me). New products resulting from the action of [Et₃O][BF₄] on a mixture of di- and tri-nuclear anionic iron complexes containing a bridging ethene or alkyne ligand. / Yanez, R.; Ros, J.; Solans, X. et al.
In: Journal of Organometallic Chemistry, Vol. 388, Núm. 1-2, 15.05.1990, pàg. 169-174.

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

TY - JOUR

T1 - Synthesis of Fe2(CO)6(μ-CRCR′COEtH) complexes (R = R′ = Ph; R = Ph, R′ = Me). New products resulting from the action of [Et3O][BF4] on a mixture of di- and tri-nuclear anionic iron complexes containing a bridging ethene or alkyne ligand

AU - Yanez, R.

AU - Ros, J.

AU - Solans, X.

AU - Font-Bardia, M.

AU - Mathieu, R.

PY - 1990/5/15

Y1 - 1990/5/15

N2 - The action of [Et3O][BF4] with the mixture resulting from the reaction of the RCCR′ alkynes (R = R′ = Ph; R = Ph, R′ = Me) with [PPh4][HFe3(CO)11] in boiling THF or acetone leads to the formation of Fe2(CO)6(μ-CRCR′C(OEt)H) complexes as the main products. For the complex with R′ = Me, the X-ray structure of the complex shows that the Fe2(CO)6 unit is bridged by the organic fragment, which is η1η3-bonded through the carbons of the chain to the two iron atoms and also bonded to an iron atom through the oxygen of the ethoxy group. © 1989.

AB - The action of [Et3O][BF4] with the mixture resulting from the reaction of the RCCR′ alkynes (R = R′ = Ph; R = Ph, R′ = Me) with [PPh4][HFe3(CO)11] in boiling THF or acetone leads to the formation of Fe2(CO)6(μ-CRCR′C(OEt)H) complexes as the main products. For the complex with R′ = Me, the X-ray structure of the complex shows that the Fe2(CO)6 unit is bridged by the organic fragment, which is η1η3-bonded through the carbons of the chain to the two iron atoms and also bonded to an iron atom through the oxygen of the ethoxy group. © 1989.

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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Yanez R, Ros J, Solans X, Font-Bardia M, Mathieu R. Synthesis of Fe₂(CO)₆(μ-CRCR′COEtH) complexes (R = R′ = Ph; R = Ph, R′ = Me). New products resulting from the action of [Et₃O][BF₄] on a mixture of di- and tri-nuclear anionic iron complexes containing a bridging ethene or alkyne ligand. Journal of Organometallic Chemistry. 1990 maig 15;388(1-2):169-174. doi: 10.1016/0022-328X(90)85358-6