TY - JOUR
T1 - Synthesis of Chiral Functionalised Cyclobutylpyrrolidines and Cyclobutylamino Alcohols from (-)-( S )-Verbenone - Applications in the Stabilisation of Ruthenium Nanocatalysts
T2 - Chiral Functionalised Cyclobutylpyrrolidines and Cyclobutylamino Alcohols
AU - Aguilera, Jordi
AU - Favier, Isabelle
AU - Sans, Marta
AU - Mor, Àlex
AU - Álvarez-Larena, Ángel
AU - Illa, Ona
AU - Gómez, Montserrat
AU - Ortuño, Rosa M.
PY - 2015/1/1
Y1 - 2015/1/1
N2 - © 2015 Wiley-VCH Verlag GmbH & Co. KGaA. Stereoselective and efficient synthetic routes to pyrrolidines and amino alcohols anchored to chiral polysubstituted cyclobutane moieties have been developed from (-)-(S)-verbenone. These original frameworks, in particular the diamines and amino alcohols, are appropriate stabilisers of metallic nanoparticles, especially for the synthesis of ruthenium nanomaterials, which found catalytic applications in the hydrogenation of arenes and nitrobenzene derivatives to afford selectively the corresponding cyclohexane or aniline derivatives.
AB - © 2015 Wiley-VCH Verlag GmbH & Co. KGaA. Stereoselective and efficient synthetic routes to pyrrolidines and amino alcohols anchored to chiral polysubstituted cyclobutane moieties have been developed from (-)-(S)-verbenone. These original frameworks, in particular the diamines and amino alcohols, are appropriate stabilisers of metallic nanoparticles, especially for the synthesis of ruthenium nanomaterials, which found catalytic applications in the hydrogenation of arenes and nitrobenzene derivatives to afford selectively the corresponding cyclohexane or aniline derivatives.
KW - Amino alcohols
KW - Heterogeneous catalysis
KW - Hydrogenation
KW - Nanoparticles
KW - Nitrogen heterocycles
KW - Ruthenium
U2 - 10.1002/ejoc.201403176
DO - 10.1002/ejoc.201403176
M3 - Article
SN - 1434-193X
VL - 2015
SP - 810
EP - 819
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
IS - 4
ER -