Synthesis, characterization, and thermoelectric properties of superconducting (BEDT-TTF)<inf>2</inf>I<inf>3</inf> nanoparticles

I. Chtioui-Gay; C. Faulmann; D. De Caro; K. Jacob; L. Valade; P. De Caro; J. Fraxedas; B. Ballesteros; E. Steven; E. S. Choi; M. Lee; S. M. Benjamin; E. Yvenou; J. P. Simonato; A. Carella

doi:10.1039/c6tc01378c

Synthesis, characterization, and thermoelectric properties of superconducting (BEDT-TTF)<inf>2</inf>I<inf>3</inf> nanoparticles

I. Chtioui-Gay, C. Faulmann, D. De Caro, K. Jacob, L. Valade, P. De Caro, J. Fraxedas, B. Ballesteros, E. Steven, E. S. Choi, M. Lee, S. M. Benjamin, E. Yvenou, J. P. Simonato, A. Carella

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© The Royal Society of Chemistry 2016. The synthesis of (BEDT-TTF)2I3 in the presence of two neutral amphiphilic molecules [N-octylfurfurylimine and 1-octanamine, N-(2-thienylmethylene)] leads to single and aggregated nanoparticles of 2 to 6 nm size. The samples contain highly crystalline nanoparticles of the βCO-(BEDT-TTF)2I3 phase, confirmed by XRD. Temperature dependent resistance and magnetic susceptibility studies evidence the superconducting transition characteristics of the βCO-(BEDT-TTF)2I3 phase. The I-V curve of a single nanoparticle aggregate, measured using AFM, exhibits an expected semiconductor-like behaviour. Thermoelectric studies led to a ZT of 1.47 × 10-3 at 300 K.

Idioma original	Anglès
Pàgines (de-a)	7449-7454
Revista	Journal of Materials Chemistry C
Volum	4
Número	31
DOIs	https://doi.org/10.1039/c6tc01378c
Estat de la publicació	Publicada - 1 de gen. 2016

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10.1039/c6tc01378c

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Chtioui-Gay, I., Faulmann, C., De Caro, D., Jacob, K., Valade, L., De Caro, P., Fraxedas, J., Ballesteros, B., Steven, E., Choi, E. S., Lee, M., Benjamin, S. M., Yvenou, E., Simonato, J. P., & Carella, A. (2016). Synthesis, characterization, and thermoelectric properties of superconducting (BEDT-TTF)<inf>2</inf>I<inf>3</inf> nanoparticles. Journal of Materials Chemistry C, 4(31), 7449-7454. https://doi.org/10.1039/c6tc01378c

@article{e3196ba7b2c04fb88a6d0624778bfb62,

title = "Synthesis, characterization, and thermoelectric properties of superconducting (BEDT-TTF)2I3 nanoparticles",

abstract = "{\textcopyright} The Royal Society of Chemistry 2016. The synthesis of (BEDT-TTF)2I3 in the presence of two neutral amphiphilic molecules [N-octylfurfurylimine and 1-octanamine, N-(2-thienylmethylene)] leads to single and aggregated nanoparticles of 2 to 6 nm size. The samples contain highly crystalline nanoparticles of the βCO-(BEDT-TTF)2I3 phase, confirmed by XRD. Temperature dependent resistance and magnetic susceptibility studies evidence the superconducting transition characteristics of the βCO-(BEDT-TTF)2I3 phase. The I-V curve of a single nanoparticle aggregate, measured using AFM, exhibits an expected semiconductor-like behaviour. Thermoelectric studies led to a ZT of 1.47 × 10-3 at 300 K.",

author = "I. Chtioui-Gay and C. Faulmann and \{De Caro\}, D. and K. Jacob and L. Valade and \{De Caro\}, P. and J. Fraxedas and B. Ballesteros and E. Steven and Choi, \{E. S.\} and M. Lee and Benjamin, \{S. M.\} and E. Yvenou and Simonato, \{J. P.\} and A. Carella",

year = "2016",

month = jan,

day = "1",

doi = "10.1039/c6tc01378c",

language = "English",

volume = "4",

pages = "7449--7454",

journal = "Journal of Materials Chemistry C",

issn = "2050-7534",

publisher = "Royal Society of Chemistry",

number = "31",

}

Chtioui-Gay, I, Faulmann, C, De Caro, D, Jacob, K, Valade, L, De Caro, P, Fraxedas, J, Ballesteros, B, Steven, E, Choi, ES, Lee, M, Benjamin, SM, Yvenou, E, Simonato, JP & Carella, A 2016, 'Synthesis, characterization, and thermoelectric properties of superconducting (BEDT-TTF)<inf>2</inf>I<inf>3</inf> nanoparticles', Journal of Materials Chemistry C, vol. 4, núm. 31, pàg. 7449-7454. https://doi.org/10.1039/c6tc01378c

TY - JOUR

T1 - Synthesis, characterization, and thermoelectric properties of superconducting (BEDT-TTF)2I3 nanoparticles

AU - Chtioui-Gay, I.

AU - Faulmann, C.

AU - De Caro, D.

AU - Jacob, K.

AU - Valade, L.

AU - De Caro, P.

AU - Fraxedas, J.

AU - Ballesteros, B.

AU - Steven, E.

AU - Choi, E. S.

AU - Lee, M.

AU - Benjamin, S. M.

AU - Yvenou, E.

AU - Simonato, J. P.

AU - Carella, A.

PY - 2016/1/1

Y1 - 2016/1/1

N2 - © The Royal Society of Chemistry 2016. The synthesis of (BEDT-TTF)2I3 in the presence of two neutral amphiphilic molecules [N-octylfurfurylimine and 1-octanamine, N-(2-thienylmethylene)] leads to single and aggregated nanoparticles of 2 to 6 nm size. The samples contain highly crystalline nanoparticles of the βCO-(BEDT-TTF)2I3 phase, confirmed by XRD. Temperature dependent resistance and magnetic susceptibility studies evidence the superconducting transition characteristics of the βCO-(BEDT-TTF)2I3 phase. The I-V curve of a single nanoparticle aggregate, measured using AFM, exhibits an expected semiconductor-like behaviour. Thermoelectric studies led to a ZT of 1.47 × 10-3 at 300 K.

AB - © The Royal Society of Chemistry 2016. The synthesis of (BEDT-TTF)2I3 in the presence of two neutral amphiphilic molecules [N-octylfurfurylimine and 1-octanamine, N-(2-thienylmethylene)] leads to single and aggregated nanoparticles of 2 to 6 nm size. The samples contain highly crystalline nanoparticles of the βCO-(BEDT-TTF)2I3 phase, confirmed by XRD. Temperature dependent resistance and magnetic susceptibility studies evidence the superconducting transition characteristics of the βCO-(BEDT-TTF)2I3 phase. The I-V curve of a single nanoparticle aggregate, measured using AFM, exhibits an expected semiconductor-like behaviour. Thermoelectric studies led to a ZT of 1.47 × 10-3 at 300 K.

UR - https://www.scopus.com/pages/publications/84981268260

U2 - 10.1039/c6tc01378c

DO - 10.1039/c6tc01378c

M3 - Article

SN - 2050-7534

VL - 4

SP - 7449

EP - 7454

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

IS - 31

ER -

Synthesis, characterization, and thermoelectric properties of superconducting (BEDT-TTF)<inf>2</inf>I<inf>3</inf> nanoparticles

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