Synthesis and structure of novel Ru^II-N≡C-Me complexes and their activity towards nitrile hydrolysis: An examination of ligand effects

Keyphrases

• MeCN 100%
• Ligand Effects 100%
• Nitrile Hydrolysis 100%
• Dppe 75%
• UV-VIS Spectroscopy 50%
• 1,10-Phenanthroline 50%
• Electrochemical Techniques 25%
• Synthetic Intermediate 25%
• Solid State 25%
• Chelates 25%
• Hydrolysis 25%
• CSIRO 25%
• 2,2′-Bipyridine 25%
• Cyclic Voltammetry 25%
• Auxiliary Ligand 25%
• X-ray Diffraction (XRD) Analysis 25%
• Temperature Range 25%
• Second-order Rate Constant 25%
• Rate-determining Step 25%
• Metal Center 25%
• Acetonitrile 25%
• Bidentate Ligands 25%
• 1D NMR 25%
• Activation Parameters 25%
• Ethylamine 25%
• Distorted Octahedral Geometry 25%
• 1,2-Bis(4-pyridyl)ethane 25%
• Ru Metal 25%
• 2D NMR Techniques 25%
• Basic Hydrolysis 25%

Chemistry

• Nitrile 100%
• Enzymatic Hydrolysis 100%
• UV/VIS Spectroscopy 66%
• 1,10-phenanthroline 66%
• X-Ray Diffraction 33%
• Bipyridine 33%
• Cyclic Voltammetry 33%
• Rate Constant 33%
• Single Crystal X-Ray Diffraction 33%
• Rate-Determining Step 33%
• Two-Dimensional NMR 33%
• 1D NMR Spectroscopy 33%
• Ethylamine 33%
• 1,2-bis(diphenylphosphino)ethane 33%
• Spectroscopy 33%
• Acetonitrile 33%
• electronics 33%
• chelate 33%