TY - JOUR
T1 - Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe2(CO)6(μ-PPh2(μ-CPhCPhH)]
AU - Yáñez, Ramón
AU - Ros, Josep
AU - Mathieu, René
AU - Solans, Xavier
AU - Font-Bardia, Mercé
PY - 1990/6/12
Y1 - 1990/6/12
N2 - Treatment of [Fe2(CO)6(μ-CO)(μ-CRCR′H)]- (R = R′ = Ph, H an RPh, R′ = Me) with PPh2Cl in CH2Cl2 in the presence of TlBF4 gives complexes of the type [Fe2(CO)6(μ-PPh2)(μ-CRCR′H) ], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe2(CO)6(μ-CO)(μ-PPh2)]- with CF3COOH and acetylenes. The crystal structure of the complex [Fe2(CO)6(μ-PPh2)(μ-CPHCPhH)] is reported. © 1990.
AB - Treatment of [Fe2(CO)6(μ-CO)(μ-CRCR′H)]- (R = R′ = Ph, H an RPh, R′ = Me) with PPh2Cl in CH2Cl2 in the presence of TlBF4 gives complexes of the type [Fe2(CO)6(μ-PPh2)(μ-CRCR′H) ], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe2(CO)6(μ-CO)(μ-PPh2)]- with CF3COOH and acetylenes. The crystal structure of the complex [Fe2(CO)6(μ-PPh2)(μ-CPHCPhH)] is reported. © 1990.
U2 - 10.1016/0022-328X(90)85413-S
DO - 10.1016/0022-328X(90)85413-S
M3 - Article
SN - 0022-328X
VL - 389
SP - 219
EP - 226
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -