Synthesis and structural characterization of a dendrimer model compound based on a cyclotriphosphazene core with TEMPO radicals as substituents

Elena Badetti; Vega Lloveras; Klaus Wurst; Rosa María Sebastián; Anne Marie Caminade; Jean Pierre Majoral; Jaume Veciana; José Vidal-Gancedo

doi:10.1021/ol401017c

Synthesis and structural characterization of a dendrimer model compound based on a cyclotriphosphazene core with TEMPO radicals as substituents

Elena Badetti, Vega Lloveras, Klaus Wurst, Rosa María Sebastián, Anne Marie Caminade, Jean Pierre Majoral, Jaume Veciana, José Vidal-Gancedo

Departament de Química

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

41 Cites (Scopus)

Resum

The synthesis of the 3Gc0T zero generation dendrimer with a cyclotriphosphazene core functionalized with nitroxyl radicals in its six branches has been performed. The radical units have been used as probes to determine the orientation of the six branches in solution experimentally by Electron Paramagnetic Resonance (EPR) spectroscopy compared with the structure obtained in the solid state by X-ray diffraction. The orientation of the dendrimer branches is the same in solution as in the solid state. © 2013 American Chemical Society.

Idioma original	Anglès
Pàgines (de-a)	3490-3493
Revista	Organic Letters
Volum	15
Número	14
DOIs	https://doi.org/10.1021/ol401017c
Estat de la publicació	Publicada - 19 de jul. 2013

Accés al document

10.1021/ol401017c

Altres arxius i enllaços

https://www.scopus.com/pages/publications/84880519139

Com citar-ho

@article{3f86795a651740238bee49c46c012bfc,

title = "Synthesis and structural characterization of a dendrimer model compound based on a cyclotriphosphazene core with TEMPO radicals as substituents",

abstract = "The synthesis of the 3Gc0T zero generation dendrimer with a cyclotriphosphazene core functionalized with nitroxyl radicals in its six branches has been performed. The radical units have been used as probes to determine the orientation of the six branches in solution experimentally by Electron Paramagnetic Resonance (EPR) spectroscopy compared with the structure obtained in the solid state by X-ray diffraction. The orientation of the dendrimer branches is the same in solution as in the solid state. {\textcopyright} 2013 American Chemical Society.",

author = "Elena Badetti and Vega Lloveras and Klaus Wurst and Sebasti{\'a}n, \{Rosa Mar{\'i}a\} and Caminade, \{Anne Marie\} and Majoral, \{Jean Pierre\} and Jaume Veciana and Jos{\'e} Vidal-Gancedo",

year = "2013",

month = jul,

day = "19",

doi = "10.1021/ol401017c",

language = "English",

volume = "15",

pages = "3490--3493",

number = "14",

}

TY - JOUR

T1 - Synthesis and structural characterization of a dendrimer model compound based on a cyclotriphosphazene core with TEMPO radicals as substituents

AU - Badetti, Elena

AU - Lloveras, Vega

AU - Wurst, Klaus

AU - Sebastián, Rosa María

AU - Caminade, Anne Marie

AU - Majoral, Jean Pierre

AU - Veciana, Jaume

AU - Vidal-Gancedo, José

PY - 2013/7/19

Y1 - 2013/7/19

N2 - The synthesis of the 3Gc0T zero generation dendrimer with a cyclotriphosphazene core functionalized with nitroxyl radicals in its six branches has been performed. The radical units have been used as probes to determine the orientation of the six branches in solution experimentally by Electron Paramagnetic Resonance (EPR) spectroscopy compared with the structure obtained in the solid state by X-ray diffraction. The orientation of the dendrimer branches is the same in solution as in the solid state. © 2013 American Chemical Society.

AB - The synthesis of the 3Gc0T zero generation dendrimer with a cyclotriphosphazene core functionalized with nitroxyl radicals in its six branches has been performed. The radical units have been used as probes to determine the orientation of the six branches in solution experimentally by Electron Paramagnetic Resonance (EPR) spectroscopy compared with the structure obtained in the solid state by X-ray diffraction. The orientation of the dendrimer branches is the same in solution as in the solid state. © 2013 American Chemical Society.

UR - https://www.scopus.com/pages/publications/84880519139

U2 - 10.1021/ol401017c

DO - 10.1021/ol401017c

M3 - Article

SN - 1523-7060

VL - 15

SP - 3490

EP - 3493

JO - Organic Letters

JF - Organic Letters

IS - 14

ER -

Synthesis and structural characterization of a dendrimer model compound based on a cyclotriphosphazene core with TEMPO radicals as substituents

Resum

Accés al document

Altres arxius i enllaços

Fingerprint

Com citar-ho