Synthesis and structural characterisation of a new cobalt(II) pentanuclear complex with a tetranucleating pyrazole-derived ligand

Josefina Pons Picart, Francisco Javier Sanchez, Jaume Casabó, Jordi Rius, Angel Alvarez-Larena, Josep Ros

Producció científica: Contribució a una revistaArticleRecercaAvaluat per experts

14 Cites (Scopus)

Resum

Reaction of Co(O2CMe)2·4H2O with HL0 (3,5-bis(6-methyl-2-pyridyl)pyrazole) yielded unexpectedly a new pentanuclear compound Co5(L0)2 (O2CMe)8(H2O)2. The complex has been characterised by elemental analyses, IR and single-crystal X-ray diffraction. The molecular structure is unusual and consists of a centrosymmetrical pentanuclear Co(II) complex containing two 3,5-bis(6-methyl-2-pyridyl)pyrazole ligands, eight MeCOO- anions and two H2O molecules, all co-ordinates. © 2002 Elsevier Science B.V. All rights reserved.
Idioma originalEnglish
Pàgines (de-a)130-133
RevistaInorganic Chemistry Communications
Volum5
Número2
DOIs
Estat de la publicacióPublicada - 12 de febr. 2002

Fingerprint

Navegar pels temes de recerca de 'Synthesis and structural characterisation of a new cobalt(II) pentanuclear complex with a tetranucleating pyrazole-derived ligand'. Junts formen un fingerprint únic.

Com citar-ho