Synthesis and Separation of Atropisomers of 9,10-Dipivaloylanthracene and 9,10-Bis(1-imino-2,2-dimethylpropyl)anthracene. Structural Study by NMR, Molecular Mechanics, and X-ray Diffraction

A. Port; M. Moragas; X. Sánchez-Ruiz; C. Jaime; A. Virgili; A. Alvarez-Larena; J. F. Piniella

doi:10.1021/jo961166e

Synthesis and Separation of Atropisomers of 9,10-Dipivaloylanthracene and 9,10-Bis(1-imino-2,2-dimethylpropyl)anthracene. Structural Study by NMR, Molecular Mechanics, and X-ray Diffraction

A. Port, M. Moragas, X. Sánchez-Ruiz, C. Jaime, A. Virgili, A. Alvarez-Larena, J. F. Piniella

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8 Cites (Scopus)

Resum

Cisoid and transoid conformations of 9,10-dipivaloylanthracene and 9,10-bis(1-imino-2,2-dimethylpropyl)anthracene were separated and detected for the former and isolated for the latter at room temperature. The transformation between two atropisomers was studied by NMR and modeled by MM methods. X-ray diffraction was performed for the imino derivatives.

Idioma original	English
Pàgines (de-a)	899-902
Revista	Journal of Organic Chemistry
Volum	62
Número	4
DOIs	https://doi.org/10.1021/jo961166e
Estat de la publicació	Publicada - 1 de gen. 1997

Accés al document

10.1021/jo961166e

CCDC 119106: Experimental Crystal Structure Determination
Port Casamitjana, A. (Creador), Moragas Rodriguez, M. (Creador), Sánchez Ruiz, J. (Col·laborador), Jaime, C. (Creador), Virgili, A. (Creador), Álvarez Larena, A. (Creador) & Piniella, J. F. (Creador), Cambridge Crystallographic Data Centre, 21 de juny 1999
DOI: 10.5517/cc3zy44, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc3zy44&sid=DataCite
Conjunt de dades: Datasets
CCDC 119107: Experimental Crystal Structure Determination
Port Casamitjana, A. (Creador), Moragas Rodriguez, M. (Creador), Sánchez Ruiz, J. (Col·laborador), Jaime, C. (Creador), Virgili, A. (Creador), Álvarez Larena, A. (Creador) & Piniella, J. F. (Creador), Cambridge Crystallographic Data Centre, 21 de juny 1999
DOI: 10.5517/cc3zy55, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc3zy55&sid=DataCite
Conjunt de dades: Datasets

Com citar-ho

Port, A., Moragas, M., Sánchez-Ruiz, X., Jaime, C., Virgili, A., Alvarez-Larena, A., & Piniella, J. F. (1997). Synthesis and Separation of Atropisomers of 9,10-Dipivaloylanthracene and 9,10-Bis(1-imino-2,2-dimethylpropyl)anthracene. Structural Study by NMR, Molecular Mechanics, and X-ray Diffraction. Journal of Organic Chemistry, 62(4), 899-902. https://doi.org/10.1021/jo961166e

@article{a796b93bffed46fba704339f3f904445,

title = "Synthesis and Separation of Atropisomers of 9,10-Dipivaloylanthracene and 9,10-Bis(1-imino-2,2-dimethylpropyl)anthracene. Structural Study by NMR, Molecular Mechanics, and X-ray Diffraction",

abstract = "Cisoid and transoid conformations of 9,10-dipivaloylanthracene and 9,10-bis(1-imino-2,2-dimethylpropyl)anthracene were separated and detected for the former and isolated for the latter at room temperature. The transformation between two atropisomers was studied by NMR and modeled by MM methods. X-ray diffraction was performed for the imino derivatives.",

author = "A. Port and M. Moragas and X. S{\'a}nchez-Ruiz and C. Jaime and A. Virgili and A. Alvarez-Larena and Piniella, {J. F.}",

year = "1997",

month = jan,

day = "1",

doi = "10.1021/jo961166e",

language = "English",

volume = "62",

pages = "899--902",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "4",

}

Port, A, Moragas, M, Sánchez-Ruiz, X, Jaime, C, Virgili, A, Alvarez-Larena, A & Piniella, JF 1997, 'Synthesis and Separation of Atropisomers of 9,10-Dipivaloylanthracene and 9,10-Bis(1-imino-2,2-dimethylpropyl)anthracene. Structural Study by NMR, Molecular Mechanics, and X-ray Diffraction', Journal of Organic Chemistry, vol. 62, núm. 4, pàg. 899-902. https://doi.org/10.1021/jo961166e

Synthesis and Separation of Atropisomers of 9,10-Dipivaloylanthracene and 9,10-Bis(1-imino-2,2-dimethylpropyl)anthracene. Structural Study by NMR, Molecular Mechanics, and X-ray Diffraction. / Port, A.; Moragas, M.; Sánchez-Ruiz, X. et al.
In: Journal of Organic Chemistry, Vol. 62, Núm. 4, 01.01.1997, pàg. 899-902.

Producció científica: Contribució a una revista › Article › Recerca › Avaluat per experts

TY - JOUR

T1 - Synthesis and Separation of Atropisomers of 9,10-Dipivaloylanthracene and 9,10-Bis(1-imino-2,2-dimethylpropyl)anthracene. Structural Study by NMR, Molecular Mechanics, and X-ray Diffraction

AU - Port, A.

AU - Moragas, M.

AU - Sánchez-Ruiz, X.

AU - Jaime, C.

AU - Virgili, A.

AU - Alvarez-Larena, A.

AU - Piniella, J. F.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Cisoid and transoid conformations of 9,10-dipivaloylanthracene and 9,10-bis(1-imino-2,2-dimethylpropyl)anthracene were separated and detected for the former and isolated for the latter at room temperature. The transformation between two atropisomers was studied by NMR and modeled by MM methods. X-ray diffraction was performed for the imino derivatives.

AB - Cisoid and transoid conformations of 9,10-dipivaloylanthracene and 9,10-bis(1-imino-2,2-dimethylpropyl)anthracene were separated and detected for the former and isolated for the latter at room temperature. The transformation between two atropisomers was studied by NMR and modeled by MM methods. X-ray diffraction was performed for the imino derivatives.

U2 - 10.1021/jo961166e

DO - 10.1021/jo961166e

M3 - Article

SN - 0022-3263

VL - 62

SP - 899

EP - 902

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 4

ER -

Synthesis and Separation of Atropisomers of 9,10-Dipivaloylanthracene and 9,10-Bis(1-imino-2,2-dimethylpropyl)anthracene. Structural Study by NMR, Molecular Mechanics, and X-ray Diffraction

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Conjunts de dades

CCDC 119106: Experimental Crystal Structure Determination

CCDC 119107: Experimental Crystal Structure Determination

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