Synthesis and characterization of mixed-phosphine osmium polyhydrides: Hydrogen delocalization in [OsH₅P₃]⁺ systems

Keyphrases

• Phosphine 100%
• Dihydrogen 100%
• Molecular Hydrogen 100%
• Delocalization 100%
• Osmium 100%
• Polyhydride 100%
• Et3N 100%
• Osh4 100%
• Bulky Phosphines 100%
• Thermodynamics 50%
• Methanol 50%
• Toluene 50%
• X Ray Diffraction 50%
• Hydrogen Atom 50%
• Deprotonation 50%
• Experimental Structure 50%
• Repulsion 50%
• QM-MM 50%
• HBF4 50%
• Model Complex 50%
• Acidolysis 50%
• Y-shaped 50%
• Osh6 50%
• Very Low Energy 50%
• Osh3 50%
• Hydrogen Molecule 50%
• Steric Congestion 50%
• Low Coordination number 50%
• Static Representation 50%

Chemistry

• Dihydrogen 100%
• Osmium 100%
• formation 100%
• X-Ray Diffraction 50%
• Deprotonation 50%
• Methanol 50%
• Acidolysis 50%
• Osmium Atom 50%
• Coordination Number 50%