TY - JOUR
T1 - Synthesis and characterization of cyano-bridged compounds (IV) Chromium-nickel, chromium-palladium and chromium-platinum dinuclear complexes
AU - Ribas, J.
AU - Serra, M.
AU - Escuer, A.
AU - Coronas, J. M.
AU - Casabo, J.
PY - 1981/1/1
Y1 - 1981/1/1
N2 - Dinuclear complexes with μ-cyano ligand of formula [(aa)2FCrNCM(CN)3] have been obtained by heating trans-[CrF(H2O)(aa)2][M(CN)4] (aa = ethylenediamine (en); 1,3-propanediamine (tmd); M Ni(II), Pd(II), Pt(II). Chemical analyses, conductivity measurements and electronic and IR spectra justify the formulation proposed. X-Ray diffraction indicates isomorphism for the three mixed complex salts of en, and for the tmd salts. The amine part of the en complexes undergoes a trans → cis change of configuration during the formation reaction; this change is not observed for the tmd complexes. The cis-bis (ethylenediamine) fluoro (tetracyanoplatinate(II)-N) Chromium(III): Cis-[(en)2FCrNCPt(CN)3] shows Pt-Pt interaction both in the solid state and in solution. © 1981.
AB - Dinuclear complexes with μ-cyano ligand of formula [(aa)2FCrNCM(CN)3] have been obtained by heating trans-[CrF(H2O)(aa)2][M(CN)4] (aa = ethylenediamine (en); 1,3-propanediamine (tmd); M Ni(II), Pd(II), Pt(II). Chemical analyses, conductivity measurements and electronic and IR spectra justify the formulation proposed. X-Ray diffraction indicates isomorphism for the three mixed complex salts of en, and for the tmd salts. The amine part of the en complexes undergoes a trans → cis change of configuration during the formation reaction; this change is not observed for the tmd complexes. The cis-bis (ethylenediamine) fluoro (tetracyanoplatinate(II)-N) Chromium(III): Cis-[(en)2FCrNCPt(CN)3] shows Pt-Pt interaction both in the solid state and in solution. © 1981.
UR - https://www.scopus.com/pages/publications/11644318295
U2 - 10.1016/0022-1902(81)80073-5
DO - 10.1016/0022-1902(81)80073-5
M3 - Article
SN - 0022-1902
VL - 43
SP - 3113
EP - 3118
JO - Journal of Inorganic and Nuclear Chemistry
JF - Journal of Inorganic and Nuclear Chemistry
IS - 12
ER -