Synthesis and characterization of a stable cyclic gem-bis(phosphaylide): A 4π-electron three-membered heterocycle

Nicola Dellus; Tsuyoshi Kato; Nathalie Saffon-Merceron; Vicenç Branchadell; Antoine Baceiredo

doi:10.1021/ic2013182

Synthesis and characterization of a stable cyclic gem-bis(phosphaylide): A 4π-electron three-membered heterocycle

Nicola Dellus, Tsuyoshi Kato, Nathalie Saffon-Merceron, Vicenç Branchadell, Antoine Baceiredo

Departament de Química

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The mixed P,S-bisylide 1 reacts with phosphenium salts, affording phosphoniophosphinocarbenes, with elimination of diphenyl sulfide. Using a more compact cyclic phosphenium cation, the reaction leads to the formation of an original three-membered heterocycle featuring a gem-bisylide function. This molecule represents the first isolable analogue of the phosphirenyl anion derivative. © 2011 American Chemical Society.

Idioma original	Anglès
Pàgines (de-a)	7949-7951
Revista	Inorganic Chemistry
Volum	50
Número	17
DOIs	https://doi.org/10.1021/ic2013182
Estat de la publicació	Publicada - 5 de set. 2011

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title = "Synthesis and characterization of a stable cyclic gem-bis(phosphaylide): A 4π-electron three-membered heterocycle",

abstract = "The mixed P,S-bisylide 1 reacts with phosphenium salts, affording phosphoniophosphinocarbenes, with elimination of diphenyl sulfide. Using a more compact cyclic phosphenium cation, the reaction leads to the formation of an original three-membered heterocycle featuring a gem-bisylide function. This molecule represents the first isolable analogue of the phosphirenyl anion derivative. {\textcopyright} 2011 American Chemical Society.",

author = "Nicola Dellus and Tsuyoshi Kato and Nathalie Saffon-Merceron and Vicen{\c c} Branchadell and Antoine Baceiredo",

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T1 - Synthesis and characterization of a stable cyclic gem-bis(phosphaylide): A 4π-electron three-membered heterocycle

AU - Dellus, Nicola

AU - Kato, Tsuyoshi

AU - Saffon-Merceron, Nathalie

AU - Branchadell, Vicenç

AU - Baceiredo, Antoine

PY - 2011/9/5

Y1 - 2011/9/5

N2 - The mixed P,S-bisylide 1 reacts with phosphenium salts, affording phosphoniophosphinocarbenes, with elimination of diphenyl sulfide. Using a more compact cyclic phosphenium cation, the reaction leads to the formation of an original three-membered heterocycle featuring a gem-bisylide function. This molecule represents the first isolable analogue of the phosphirenyl anion derivative. © 2011 American Chemical Society.

AB - The mixed P,S-bisylide 1 reacts with phosphenium salts, affording phosphoniophosphinocarbenes, with elimination of diphenyl sulfide. Using a more compact cyclic phosphenium cation, the reaction leads to the formation of an original three-membered heterocycle featuring a gem-bisylide function. This molecule represents the first isolable analogue of the phosphirenyl anion derivative. © 2011 American Chemical Society.

UR - https://www.scopus.com/pages/publications/80052252495

U2 - 10.1021/ic2013182

DO - 10.1021/ic2013182

M3 - Article

SN - 0020-1669

VL - 50

SP - 7949

EP - 7951

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

Synthesis and characterization of a stable cyclic gem-bis(phosphaylide): A 4π-electron three-membered heterocycle

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