Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst

Marcial Moreno-Mañas; Roser Pleixats; Anna Serra-Muns

doi:10.1055/s-2006-948173

Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst

Marcial Moreno-Mañas, Roser Pleixats, Anna Serra-Muns

Departament de Química

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Resum

The combination of a bulky aliphatic phosphine, e.g. tricyclohexylphosphine or the tetrafluoroborate salt of tri-tert-butylphosphine, with the Pd(0) complex of a 15-membered triolefinic macrocycle is an excellent catalyst for the Suzuki cross-coupling of aryl and heteroaryl bromides and chlorides. The palladium can be recovered in the form of the initial complex. © Georg Thieme Verlag Stuttgart.

Idioma original	Anglès
Pàgines (de-a)	3001-3004
Revista	Synlett
Número	18
DOIs	https://doi.org/10.1055/s-2006-948173
Estat de la publicació	Publicada - 3 de nov. 2006

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10.1055/s-2006-948173

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@article{b6bb68ee3c6a47ebb9208590531c9467,

title = "Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst",

abstract = "The combination of a bulky aliphatic phosphine, e.g. tricyclohexylphosphine or the tetrafluoroborate salt of tri-tert-butylphosphine, with the Pd(0) complex of a 15-membered triolefinic macrocycle is an excellent catalyst for the Suzuki cross-coupling of aryl and heteroaryl bromides and chlorides. The palladium can be recovered in the form of the initial complex. {\textcopyright} Georg Thieme Verlag Stuttgart.",

keywords = "Catalysis by palladium, Macrocycle, Olefin complex, Recovery",

author = "Marcial Moreno-Ma{\~n}as and Roser Pleixats and Anna Serra-Muns",

year = "2006",

month = nov,

day = "3",

doi = "10.1055/s-2006-948173",

language = "English",

pages = "3001--3004",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "18",

}

TY - JOUR

T1 - Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst

AU - Moreno-Mañas, Marcial

AU - Pleixats, Roser

AU - Serra-Muns, Anna

PY - 2006/11/3

Y1 - 2006/11/3

N2 - The combination of a bulky aliphatic phosphine, e.g. tricyclohexylphosphine or the tetrafluoroborate salt of tri-tert-butylphosphine, with the Pd(0) complex of a 15-membered triolefinic macrocycle is an excellent catalyst for the Suzuki cross-coupling of aryl and heteroaryl bromides and chlorides. The palladium can be recovered in the form of the initial complex. © Georg Thieme Verlag Stuttgart.

AB - The combination of a bulky aliphatic phosphine, e.g. tricyclohexylphosphine or the tetrafluoroborate salt of tri-tert-butylphosphine, with the Pd(0) complex of a 15-membered triolefinic macrocycle is an excellent catalyst for the Suzuki cross-coupling of aryl and heteroaryl bromides and chlorides. The palladium can be recovered in the form of the initial complex. © Georg Thieme Verlag Stuttgart.

KW - Catalysis by palladium

KW - Macrocycle

KW - Olefin complex

KW - Recovery

U2 - 10.1055/s-2006-948173

DO - 10.1055/s-2006-948173

M3 - Article

SN - 0936-5214

SP - 3001

EP - 3004

JO - Synlett

JF - Synlett

IS - 18

ER -

Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst

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