Studies on structurally simple α,β-butenolides. III. Behaviour of (-)-(s)-σ-heterosubstituted γ-methyl-α,β-butenolides towards nucleophiles. Protoanemonin as intermediate in an eliminati

P. Camps; J. Cardellach; J. Corbera; J. Font; R. M. Ortuño; O. Ponsatí

doi:10.1016/S0040-4020(01)88539-2

Studies on structurally simple α,β-butenolides. III. Behaviour of (-)-(s)-σ-heterosubstituted γ-methyl-α,β-butenolides towards nucleophiles. Protoanemonin as intermediate in an eliminati

P. Camps, J. Cardellach, J. Corbera, J. Font, R. M. Ortuño, O. Ponsatí

Departament de Química

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The reactivity of the title compounds with different nucleophiles has been checked and it was shown that products from reaction with sodium phenylthiolate result from an elimination-addition process in which protoanemonin is the key intermediate. The synthesis of (-)-(R)-β-angelica lactone is reported for the first time. © 1983.

Idioma original	Anglès
Pàgines (de-a)	395-400
Revista	Tetrahedron
Volum	39
Número	3
DOIs	https://doi.org/10.1016/S0040-4020(01)88539-2
Estat de la publicació	Publicada - 1 de gen. 1983

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10.1016/S0040-4020(01)88539-2

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title = "Studies on structurally simple α,β-butenolides. III. Behaviour of (-)-(s)-σ-heterosubstituted γ-methyl-α,β-butenolides towards nucleophiles. Protoanemonin as intermediate in an eliminati",

abstract = "The reactivity of the title compounds with different nucleophiles has been checked and it was shown that products from reaction with sodium phenylthiolate result from an elimination-addition process in which protoanemonin is the key intermediate. The synthesis of (-)-(R)-β-angelica lactone is reported for the first time. {\textcopyright} 1983.",

author = "P. Camps and J. Cardellach and J. Corbera and J. Font and Ortu{\~n}o, {R. M.} and O. Ponsat{\'i}",

year = "1983",

month = jan,

day = "1",

doi = "10.1016/S0040-4020(01)88539-2",

language = "English",

volume = "39",

pages = "395--400",

journal = "Tetrahedron",

issn = "0040-4020",

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}

Studies on structurally simple α,β-butenolides. III. Behaviour of (-)-(s)-σ-heterosubstituted γ-methyl-α,β-butenolides towards nucleophiles. Protoanemonin as intermediate in an eliminati. / Camps, P.; Cardellach, J.; Corbera, J. et al.
In: Tetrahedron, Vol. 39, Núm. 3, 01.01.1983, pàg. 395-400.

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

TY - JOUR

T1 - Studies on structurally simple α,β-butenolides. III. Behaviour of (-)-(s)-σ-heterosubstituted γ-methyl-α,β-butenolides towards nucleophiles. Protoanemonin as intermediate in an eliminati

AU - Camps, P.

AU - Cardellach, J.

AU - Corbera, J.

AU - Font, J.

AU - Ortuño, R. M.

AU - Ponsatí, O.

PY - 1983/1/1

Y1 - 1983/1/1

N2 - The reactivity of the title compounds with different nucleophiles has been checked and it was shown that products from reaction with sodium phenylthiolate result from an elimination-addition process in which protoanemonin is the key intermediate. The synthesis of (-)-(R)-β-angelica lactone is reported for the first time. © 1983.

AB - The reactivity of the title compounds with different nucleophiles has been checked and it was shown that products from reaction with sodium phenylthiolate result from an elimination-addition process in which protoanemonin is the key intermediate. The synthesis of (-)-(R)-β-angelica lactone is reported for the first time. © 1983.

U2 - 10.1016/S0040-4020(01)88539-2

DO - 10.1016/S0040-4020(01)88539-2

M3 - Article

SN - 0040-4020

VL - 39

SP - 395

EP - 400

JO - Tetrahedron

JF - Tetrahedron

IS - 3

ER -

Studies on structurally simple α,β-butenolides. III. Behaviour of (-)-(s)-σ-heterosubstituted γ-methyl-α,β-butenolides towards nucleophiles. Protoanemonin as intermediate in an eliminati

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